Skip to main content

Structural Relaxation in Various Amorphous Metallic Alloys Studied via Direct Viscosity and Bend Stress Relaxation Measurements

  • Chapter
Glassy Metals

Abstract

This book section is a continuation of those presented in Chap. 7, theoretical bend stress relaxation considerations with respect to their relation to the viscosity. The chapter provides additional experimental proof with the aid of viscosity and bend stress relaxation measurements on Pd77.5Cu6Si16.5, Аl25La50Ni25, and Al7.5Cu17.5Ni10Zr65 glassy alloys.

The FVM interpretation of the two kinds of experimental data is possible with practically one and the same set of FVM parameters. A new method for quantitative experimental separation of viscous flow caused plastic and anelastic deformations, respectively, is developed. It is shown that the relaxation of the anelastic deformation, both under isothermal and nonisothermal conditions, can be very well described by the empirical equation of Kohlrausch-Williams-Watts.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Sestak J (1984) Thermo-physical properties of solids. Academia Prague

    Google Scholar 

  2. Metals handbook, 9th ed, vol 2, American Soc for Metals, Metal Park

    Google Scholar 

  3. Maddin R, Masumoto T (1972) Mater Sci Eng 9:153

    Article  Google Scholar 

  4. Luborsky F, Walter J (1978) Mater Sci Eng 35:255

    Article  Google Scholar 

  5. Taub A, Luborsky F (1981) Acta Metall 29: 1939

    Google Scholar 

  6. Taub A, Luborsky F (1982) Mater Sci Eng 56: 157

    Google Scholar 

  7. Koleva E, Russew K, Stojanova L (2001) Isothermal study of relaxation phenomena in Pd77.5Cu6Si16.5 metallic glass. J Mater Sci Technol 9(3):171–179

    Google Scholar 

  8. Russew K, Stojanova L, Sommer F (1999) Viscosity and thermal expansion of the Al7.5Cu17.5Ni10Zr65 bulk metallic glass. In: J. Wood et al (eds) European Congress on advanced materials and processes EUROMAT’99, Munich, 27-30.09.1999, Proceedings, Volume 8, Materials development and processing–bulk amorphous materials, undercooling and powder metallurgy. WILEY-VCH, pp 65–70

    Google Scholar 

  9. Russew K , Sommer F (1999) Relaxation phenomena in the Al7.5Cu17.5Ni10Zr65 bulk metallic glass studied by bend stress and anelastic strain relaxation under isothermal and non-isothermal conditions. In: J. Wood et al (eds) European Congress on Advanced Materials and Processes EUROMAT’99, Munich, 27-30.09.1999, Proceedings, Volume 8, Materials development and processing–bulk amorphous materials, undercooling and powder metallurgy, WILEY-VCH, pp 55–64

    Google Scholar 

  10. Russew K et al (1997) Viscous flow of amorphous Fe40Ni40Si6B14 glassy alloy studied by direct creep measurements and relaxation of bend stresses under nonisothermal conditions. Acta Mater 45(No. 5):2129–2137

    Article  Google Scholar 

  11. Chen HS (1980) Rep Prog Phys 43:353

    Article  Google Scholar 

  12. Berry BS (1978) Metallic glasses. American Society of Metals, Cleveland, p 161

    Google Scholar 

  13. Leusink GJ, van den Beukel A (1988) Acta Metall 36: 3019

    Google Scholar 

  14. De Hey P, Sietsma J, van den Beukel A (1996) J Non-Cryst Solids 205–207: 696

    Google Scholar 

  15. Russew K (1997) Free volume related viscous flow, relaxation of bend stresses, thermal expansion and heat capacity of glassy metals: theory and experiment. Mater Sci Eng A226–228:779–783

    Article  Google Scholar 

  16. Russew K, Stojanova L, Koleva E (1997) Structural defects and bend stress relaxation in Al25La50Ni25 glassy alloy under isothermal and nonisothermal conditions. In: 12th national conference on non-destruct 7e testing, NDT-97, Sozopol, Scientific Communications of SNU Machine Building, Vol 7, 9–12 Jun 1997, pp 177–182

    Google Scholar 

  17. Russew Kr, Sommer F (1998) Determination of the viscosity, thermal expansion, heat capacity and bend stress relaxation temperature dependence of glassy alloys–a tool for understanding of relaxation phenomena. Int J Nonequilib Process 11: 3–23

    Google Scholar 

  18. Chen HS, Turnbull D (1968) J Chem Phys 48:531

    Article  Google Scholar 

  19. Barfteld RN, Kitchener JA (1955) J Iron Steel Inst 180: 324

    Google Scholar 

  20. Cavalier G (1960) Physical chemistry of metallic solutions and intermetallic compounds, Vol II, Chem Publ, 54

    Google Scholar 

  21. McGreevy RL, Pusztal L (1988) Mol Simul 1:359

    Article  Google Scholar 

  22. Duine PA, Sietsma J, van den Beukel A (1995) Defect and diffusion forum, 117/118, 91

    Google Scholar 

  23. Russew K, Stojanova L (1990) Viscous flow of Fe82B18 amorphous alloy under continuous heating conditions. Mater Sci Eng A123:59

    Article  Google Scholar 

  24. Kissinger HE (1702) Anal Chem 29:1957

    Google Scholar 

  25. Tsao SS, Spaepen F (1985) Acta Metall 33:881

    Article  Google Scholar 

  26. Duine PA, Sietsma J, van den Beukel A (1992) Acta Metall Mater, 40,743

    Google Scholar 

  27. Berry BS (1982) Scripta Metall 16:1407

    Article  Google Scholar 

  28. van den Beukel A (1991) Phys Stat Sol (a) 128: 285

    Google Scholar 

  29. Seeger A, Schumacher D, Schilling W, Diehl J (eds) (1970) Vacancies and interstitials in metals. North Holland, Amsterdam

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Krassimir Russew .

Rights and permissions

Reprints and permissions

Copyright information

© 2016 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Russew, K., Stojanova, L. (2016). Structural Relaxation in Various Amorphous Metallic Alloys Studied via Direct Viscosity and Bend Stress Relaxation Measurements. In: Glassy Metals. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-47882-0_8

Download citation

Publish with us

Policies and ethics