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Multiphoton Processes and Attosecond Physics pp 317–322Cite as

Visualizing Correlated Dynamics of Hydrogen Atoms in Acetylene Dication by Time-Resolved Four-Body Coulomb Explosion Imaging

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Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 125))

Abstract

Ultrafast hydrogen migration in deuterated acetylene dication (C\({}_{2}{\mathrm{D}}_{2}^{2+}\)) is studied by time-resolved four-body Coulomb explosion imaging, C2D\({}_{2}^{4+}\, \rightarrow \,\,{\mathrm{D}}^{+} +{ \mathrm{C}}^{+} +{ \mathrm{C}}^{+} +{ \mathrm{D}}^{+}\), using a pair of few-cycle intense laser pulses (9 fs, 1. 3 ×1014 W/cm2). Momentum correlation of the D + ions produced by the full fragmentation process shows that (1) motions of the two deuterium atoms are strongly correlated during the isomerization and (2) the molecular structure deforms to non-planar geometries.

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Acknowledgements

This work is supported by the PRESTO fund for “Evolution of Light Generation and Manipulation” from Japan Science and Technology Agency and by the Grant in Aid (#15685001) from MEXT of Japan.

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Authors and Affiliations

  1. Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa, Nagoya, Aichi, 464-8602, Japan

    Akitaka Matsuda, Mizuho Fushitani & Akiyoshi Hishikawa

  2. RIKEN, 2-1 Hirosawa, Wako, Saitama, 351-0198, Japan

    Eiji J. Takahashi

Authors
  1. Akitaka Matsuda
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  2. Mizuho Fushitani
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  3. Eiji J. Takahashi
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  4. Akiyoshi Hishikawa
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Corresponding author

Correspondence to Akiyoshi Hishikawa .

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Editors and Affiliations

  1. Department of Chemistry, The University of Tokyo, Hongo 7-3-1, Tokyo, 113-0033, Japan

    Kaoru Yamanouchi

  2. , Extreme Photonics Research Group, RIKEN, Hirosawa, Wako-shi 2-1, Saitama, 351-0198, Japan

    Midorikawa Katsumi

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© 2012 Springer-Verlag Berlin Heidelberg

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Matsuda, A., Fushitani, M., Takahashi, E.J., Hishikawa, A. (2012). Visualizing Correlated Dynamics of Hydrogen Atoms in Acetylene Dication by Time-Resolved Four-Body Coulomb Explosion Imaging. In: Yamanouchi, K., Katsumi, M. (eds) Multiphoton Processes and Attosecond Physics. Springer Proceedings in Physics, vol 125. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-28948-4_53

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  • DOI: https://doi.org/10.1007/978-3-642-28948-4_53

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  • Publisher Name: Springer, Berlin, Heidelberg

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