Abstract
In this chapter, we explore the possibility for spin systems to develop a type of order that breaks the O(3) spin symmetry but does not have a magnetic moment. Such ordering is usually referred to as multipolar or nematic, with quadrupolar being the simplest example. These phases have been found in S=1 Heisenberg models extended with biquadratic exchange, in certain S=1∕2 Heisenberg models with both ferromagnetic and antiferromagnetic exchange couplings, and in models with cyclic ring-exchange terms. We present theoretical and numerical methods which can be used to understand and characterize quadrupolar and nematic phases. While quadrupolar/nematic ordering is well documented in model systems, it has not yet been identified unambiguously in real materials, although there exist some promising candidates which we also review.
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Penc, K., Läuchli, A.M. (2011). Spin Nematic Phases in Quantum Spin Systems. In: Lacroix, C., Mendels, P., Mila, F. (eds) Introduction to Frustrated Magnetism. Springer Series in Solid-State Sciences, vol 164. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-10589-0_13
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