Abstract
Low voltage anode effects (LVAE) have been recognized in aluminium smelters since mid 2000s. Such events are now known to generate perfluorocarbons (PFC) emissions over time and no methodology currently exists to adequately quantify such emissions for inclusion in greenhouse gas (GHG) inventories. A novel methodology has been proposed to estimate the annual LVAE emissions from the aluminium industry (Marks & Nunez) based on a set of existing measurement data from multiple in situ gas measurement campaigns. There is currently no estimate of the contribution of LVAE emissions using this methodology for past years. This paper investigates the potential effects of adopting this approach and applying it to historic emissions inventories of PFCs. Based on historical data supplied by a select set of aluminum smelters, the total respective PFC emissions resulting from high and low voltage anode effects were calculated, allowing evaluation of the potential impact of LVAE on the total amount of PFCs reported.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Dorreen, M.M.R., (2000). Cell performance and anodic processes in aluminium smelting studied by product gas analysis. Thesis (PhD–Engineering Science)-University of Auckland.
Welch, B.J., (2011). Quantifying PFC emissions from smelter cells. in Proceedings of the 10th Australasian aluminium smelting conference. Launceston, Tasmania.
Wong, D., A.T. Tabereaux, and P. Lavoie, (2014). Anode effect phenomena during conventional AEs, low voltage propagating AEs & non-propagating AEs. Light Metals.
International Aluminium Institute, (2014). Results of the 2013 Anode Effect Survey. International Aluminium Institute: London. pp. 1–25.
Intergovernmental Panel on Climate Change (IPCC), (2006) 2006 IPCC Guidelines for National Greenhouse Gas Inventories, in Volume 3 - Industrial Processes and Product Use, J.H.Y. Katima and A. Rosland, Editors. Institute for Global Environmental Strategies (IGES): Japan. pp. 4.49–4.57.
Chen, X., et al. (2013) Investigation on formation mechanism of non-anode effect related PFC emissions from aluminum reduction cells. Light Metals, San Antonio.
Wong, D. and J. Marks, (2013). Continuous PFC emissions measured on individual 400 kA cells. Light Metals, San Antonio. pp. 865–870.
Dando, N.R., et al., (2015). Non anode effects PFC: Measurement consideration and potential impact. Light Metals, Orlando. pp 551–555.
Dion, L., et al., (2016) Prediction of low voltage tetrafluoromethane emissions based on the operating conditions of an aluminium electrolysis cell. JOM, 68(9): pp. 2472–2482.
Marks, J. and P. Nunez. (2018). Updated Factors for Calculating PFC Emissions from Primary Aluminum Production. Light Metals, Phoenix.
Dion, L., et al., (2017) Quantification of perfluorocarbons emissions during high voltage anode effects using non-linear approach. Journal of Cleaner Production, (164): pp. 357–366.
Acknowledgements
The authors would like to thank the different companies who agreed to share process data through the International Aluminium Institute in order to make this study possible.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 The Minerals, Metals & Materials Society
About this paper
Cite this paper
Dion, L., Nunez, P., Wong, D., Gaboury, S., Spirin, A. (2018). Evaluation of Time Consistency When Quantifying Emissions of Perfluorocarbons Resulting from Low Voltage Anode Effects. In: Martin, O. (eds) Light Metals 2018. TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72284-9_190
Download citation
DOI: https://doi.org/10.1007/978-3-319-72284-9_190
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-72283-2
Online ISBN: 978-3-319-72284-9
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)