Skip to main content

Intercalation of Poly[oligo(ethylene glycol)-oxalate] into Lithium Hectorite

  • Chapter
  • First Online:
Industrial Applications for Intelligent Polymers and Coatings

Abstract

Intercalation of poly[oligo(ethylene glycol)-oxalate] (POEGO) into lithium hectorite was conducted. A series of nanocomposite materials were prepared by varying the molar ratio of the polymer to the lithium hectorite. The nanocomposites were characterized using powder X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and attenuated total reflectance (ATR) spectroscopy. AC impedance spectroscopy was used to measure the ionic resistance of the nanocomposites when complexed with lithium triflate.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 249.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  1. Panero S, Settimi L, Croce F, Scrosati B (2006) New types of rechargeable lithium and lithium-ion polymer batteries. ECS Trans 1:1

    Google Scholar 

  2. Scully SF, Bissessur R (2010) Encapsulation of polymer eectrolytes into hectorite. Appl Clay Sci 47:444

    Article  Google Scholar 

  3. Blumstein A (1965) Polymerization of adsorbed monolayers. I. Preparation of the clay-polymer complex. J Polym Sci A 3:2653

    Google Scholar 

  4. Sinha Ray S, Okamoto M (2003) Polymer/layered silicate nanocomposites: a review from preparation to processing. Prog Polym Sci 28:1539

    Article  Google Scholar 

  5. Kurian M, Galvin ME, Trapa PE, Sadoway DR (2005) Single-ion conducting polymer-silicate nanocomposite electrolytes for lithium battery applications. Electrochim Acta 50:2125

    Article  Google Scholar 

  6. Scully SF, Bissessur R, MacLean KW, Dahn DC (2009) Inclusion of poly [bis(methoxyethoxyethoxy)phosphazene] into layered graphite oxide. Solid State Ionics 180:216

    Google Scholar 

  7. Xu W, Belieres J-P, Angell CA (2001) Ionic conductivity and electrochemical stability of poly[oligo(ethylene glycol)oxalate]−lithium salt complexes. Chem Mater 13:575

    Article  Google Scholar 

  8. Hoffman AS (1995) “Intelligent” polymers in medicine and biotechnology. Macromol Symp 98:645. doi:10.1002/masy.19950980156

    Google Scholar 

  9. Bissessur R, Schipper D (2008) Exfoliation and reconstruction of SnS2 layers: A synthetic route for the preparation polymer-SnS2nanomaterials. Mater Lett 62:1638

    Article  Google Scholar 

  10. Bissessur R, Scully SF (2007) Intercalation of solid polymer electrolytes into graphite oxide. Solid State Ionics 178:877

    Article  Google Scholar 

  11. Carretero MI, Pozo M (2009) Clay and non-clay minerals in the pharmaceutical industry: Part I. Excipients and medical applications. Appl Clay Sci 46:73

    Article  Google Scholar 

  12. Zhang D, Zhou C-H, Lin C-X, Tong D-S, Yu W-H (2010) Synthesis of clay minerals. Appl Clay Sci 50:1

    Article  Google Scholar 

  13. Okada A, Usuki A (1995) The chemistry of polymer-clay hybrids. Mater Sci Eng C 3:109

    Article  Google Scholar 

  14. Sandí G, Carrado KA, Joachin H, Lu W, Prakash J (2003) Polymer nanocomposites for lithium battery applications. J Power Sources 119–121:492

    Article  Google Scholar 

  15. Riley M, Fedkiw PS, Khan SA (2002) Transport properties of lithium hectorite-based composite elctrolytes. J Electrom Soc 149:A667

    Article  Google Scholar 

  16. Madejová J, Bujdák J, Janek M, Komadel P (1998) Comparative FT-IR study of structural modifications during acid treatment of dioctahedral smectites and hectorite. Spectrochim Acta Part A 54:1397

    Article  Google Scholar 

  17. Carrado KA, Forman JE, Botto RE, Winans RE (1993) Incorporation of phthalocyanines by cationic and anionic clays via ion exchange and direct synthesis. Chem Mater 5:472

    Article  Google Scholar 

  18. Voulgaris D, Petridis D (2002) Emulsifying effect of dimethyldioctadecylammonium-hectorite in polystyrene/poly(ethyl methacrylate) blends. Polymer 43:2213

    Article  Google Scholar 

  19. Kuykendall VG, Thomas JK (1990) Photophysical and photochemical studies of ruthenium (tris(bipyridine) on hectorite. J Phys Chem 94:4224

    Article  Google Scholar 

  20. Singhal RG, Capracotta MD, Martin JD, Khan SA, Fedkiw PS (2004) Transport properties of hectorite based nanocomposite single ion conductors. J Power Sources 128:247

    Article  Google Scholar 

  21. Barsoukov E, Macondald JR (2005) Impedance spectroscopy: theory, experiment, and applications (2nd edn). Wiley, Hoboken, NJ

    Google Scholar 

  22. Macdonald JR (2015) jrossmacdonald.com/levmw, accessed 25 June 2015

    Google Scholar 

  23. Monshi A, Foroughi MR, Monshi MR (2012) Modified Scherrer equation to estimate more accurately nano-crystalline size using XRD. World J Nano Sci Eng 2:154

    Article  Google Scholar 

  24. Spartan ’08, Wavefunction Inc., Irvine, CA, 2008

    Google Scholar 

  25. Meyer WH (1998) Polymer electrolytes for lithium-ion batteries. Adv Mater 10:439

    Article  Google Scholar 

  26. Ratner MA, Shriver DF (1988) Ion transport in solvent-free polymers. Chem Rev 88:109

    Article  Google Scholar 

Download references

Acknowledgments

The authors are grateful for the financial support from the Natural Sciences and Engineering Research Council (NSERC) of Canada, Canada Foundation for Innovation (CFI), Atlantic Innovation Fund (AIF) of Canada, and UPEI.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Rabin Bissessur .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 Springer International Publishing Switzerland

About this chapter

Cite this chapter

Saada, I., Bissessur, R., Dahn, D.C., Hughes, M., Trenton, V. (2016). Intercalation of Poly[oligo(ethylene glycol)-oxalate] into Lithium Hectorite. In: Hosseini, M., Makhlouf, A. (eds) Industrial Applications for Intelligent Polymers and Coatings. Springer, Cham. https://doi.org/10.1007/978-3-319-26893-4_32

Download citation

Publish with us

Policies and ethics