Abstract
Chemical variation among streams is primarily governed by the type and composition of rocks in the drainage, and by the amount and chemical composition of precipitation. In addition, human activities can significantly influence the chemical composition of rivers and streams, indirectly by changing land use and the chemical composition of precipitation, and directly by the input of agricultural, industrial, and domestic waste. This chapter focuses on the dissolved major ions (Ca2+, Na+, Mg2+, K+, HCO3-, SO42-, Cl-) and gases (O2 and CO2). Exchange with the atmosphere maintains both gases at close to their equilibrium concentrations in solution, although photosynthesis and respiration have noticeable effects in highly productive systems, and pollution in the form of excessive organic waste can deplete O2 levels. Important causes of pollution of fresh waters includes salinization due to salts used to melt ice from roads and faulty irrigation practices, increased acidity from mine drainage and fossil fuel use, legacy contaminants such as PCBs and DDT, and emerging chemicals of concern such as pharmaceuticals and personal care products, and plastic. Where pollutants occur at sufficient concentrations, their presence is detectable in organism tissue and may significantly limit populations.
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Allan, J.D., Castillo, M.M., Capps, K.A. (2021). Streamwater Chemistry. In: Stream Ecology . Springer, Cham. https://doi.org/10.1007/978-3-030-61286-3_4
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