Abstract
Ionic liquid -based (IL-based) manufacturing has the potential to revolutionize the materials industry and disrupt overdependence on petroleum-based plastics. Nature provides amazing materials at large scale; however, scalable techniques to mold and shape biomaterials have not existed at scale. Natural Fiber Welding , Inc. (NFW) has developed commercially viable processes and patent-protected materials that are scalable to meet modern challenges while reducing pollution and emissions. This chapter discusses a number of demonstrations that are being scaled for global markets as well as reviews several examples of new functionalities that can be achieved. Practical applications that create composites from waste textiles and new indigo dye processes are discussed. Examples of “exotic” materials that perform catalytic waste -water treatment and wearable energy storage are also reviewed. In all cases, NFW is able to make natural materials, such as cotton and silk , perform in new and unexpected ways. Prospects for scaling commercial applications are also discussed. With economically viable methods to reclaim, recycle, and reuse IL-based solvents , the future looks extremely bright. In the near future, industry-relevant complex natural composites will be produced at cost points that compete with incumbent synthetic plastics . This new way of manufacturing has significant potential to reduce emissions, eliminate pollution, and bring new circularity into, for example, the textile industry.
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References
Haverhals LM, Reichert WM, De Long HC, Trulove PC (2010) Natural fiber welding. Macromol Mater Eng 295(5):425–430. https://doi.org/10.1002/mame.201090008
Haverhals LM, Reichert WM, De Long HC, Trulove PC (2012) Natural fiber welding. U.S. patent no. 8202379. Awarded 19 June 2012
Swatloski RP, Spear SK, Holbrey JD, Rogers RD (2002) Dissolution of cellulose with ionic liquids. J Am Chem Soc 124:4974–4975. https://doi.org/10.1021/ja025790m
Phillips DM, Drummy LF, Conrady DG, Fox DM, Naik RR, Stone MO, Trulove PC, De Long HC, Mantz RA (2004) Dissolution and regeneration of Bombyx mori silk fibroin using ionic liquids. J Am Chem Soc 126:14350–14351. https://doi.org/10.1021/ja046079f
Haverhals LM, Sulpizio HM, Fayos ZA, Trulove MA, Reichert WM, Foley MP, De Long HC, Trulove PC (2012) Process variables that control natural fiber welding: time, temperature, and amount of ionic liquid. Cellulose 19:13–22. https://doi.org/10.1007/s10570-011-9605-0
Haverhals LM, Nevin LM, Foley MP, Brown EK, De Long HC, Trulove PC (2012) Fluorescence monitoring of ionic liquid-facilitated biopolymer mobilization and reorganization. Chem Commun 48:6417–6419. https://doi.org/10.1039/C2CC31507F
Haverhals LM, Foley MP, Brown EK, Fox DM, De Long HC, Trulove PC (2012) Natural fiber welding: ionic liquid facilitated biopolymer mobilization and reorganization. In: Visser A, Bridges N, Rogers R (eds) Ionic liquids: science and applications, ACS Symposium Series 1117, American Chemical Society. Washington, DC, Chap. 6, pp 145–166. Alternatively: ACS Symp Ser 2012, 1117:145–166. https://doi.org/10.1021/bk-2012-1117.ch006
Haverhals LM, Amstutz AK, Choi J, Tang X, Molter M, Null SJ (2018) Methods, processes, and apparatuses for producing dyed and welded substrates. U.S. patent no. 10011931. Awarded 3 July 2018
Ellen MacArthur Foundation (2017) The new plastics economy: rethinking the future of plastics and catalyzing action, pp 1–66
Ellen MacArthur Foundation (2017) A new textiles economy: redesigning fashion’s future, pp 1–150
Browne MA, Crump P, Niven SJ, Teuten E, Tonkin A, Galloway T, Thompson R (2011) Accumulation of microplastic on shorelines worldwide: sources and sinks. Environ Sci Technol 45(21):9175–9179. https://doi.org/10.1021/es201811s
Kohoutek J, Babica P, Bláha L, Maršálek B (2008) A novel approach for monitoring of cyanobacterial toxins: development and evaluation of the passive sampler for microcystins. Anal Bioanal Chem 390(4):1167–1172. https://doi.org/10.1007/s00216-007-1785-y
Cole M, Lindeque P, Fileman E, Halsband C, Goodhead R, Moger J, Galloway TS (2013) Microplastic ingestion by zooplankton. Environ Sci Technol 47(12):6646–6655. https://doi.org/10.1021/es400663f
McCormick A, Hoellein TJ, Mason SA, Schluep J, Kelly JJ (2014) Microplastic is an abundant and distinct microbial habitat in an urban river. Environ Sci Technol 48(20):11863–11871. https://doi.org/10.1021/es503610r
Rochman CM, Parnis JM, Browne MA, Serrato S, Reiner EJ, Robson M, Young T, Diamond ML, Teh SJ (2017) Direct and indirect effects of different types of microplastics on freshwater prey (Corbicula fluminea) and their predator (Acipenser transmontanus). PLoS ONE 12(11):e0187664. https://doi.org/10.1371/journal.pone.0187664
Jeong C-B, Won E-J, Kang H-M, Lee M-C, Hwang D-S, Hwang U-K, Zhou B, Souissi S, Lee S-J, Lee J-S (2016) Microplastic size-dependent toxicity, oxidative stress induction, and p-JNK and p-p38 activation in the monogonont rotifer (Brachionus koreanus). Environ Sci Technol 50(16):8849–8857. https://doi.org/10.1021/acs.est.6b01441
Smith M, Love DC, Rochman CM, Neff RA (2018) Microplastics in seafood and the implications for human health. Curr Environ Health Rep 5(3):375–386. https://doi.org/10.1007/s40572-018-0206-z
Yang D, Shi H, Li L, Li J, Jabeen K, Kolandhasamy P (2015) Microplastic pollution in table salts from China. Environ Sci Technol 49(22):13622–13627. https://doi.org/10.1021/acs.est.5b03163
https://orbmedia.org/stories/Invisibles_plastics/. Site visited 10 Jan 2019
US Department of Agriculture (2018) Cotton: world markets and trade, 11 Dec 2018 report. https://apps.fas.usda.gov/psdonline/circulars/cotton.pdf. Site visited 10 Jan 2019
US Department of Agriculture (2019) World agricultural production, 11 Dec 2018 report. https://apps.fas.usda.gov/psdonline/circulars/production.pdf. Site visited 10 Jan 2019
Wedegaertner T, Rathore K (2015) Elimination of gossypol in cottonseed will improve its utilization. Procedia Environ Sci 29:124–125. https://doi.org/10.1016/j.proenv.2015.07.212
https://www.npr.org/sections/thesalt/2018/10/17/658221327/not-just-for-cows-anymore-new-cottonseed-is-safe-for-people-to-eat. Site visited 10 Jan 2019
https://mbdc.com/. Site visited 10 Jan 2019
https://www.ellenmacarthurfoundation.org/. Site visited 10 Jan 2019
https://fashionforgood.com/. Site visited 10 Jan 2019
Edlund AM, Jones J, Lewis R, Quinn JC (2018) Economic feasibility and environmental impact of synthetic spider silk production from Escherichia coli. New Biotechnol 42:12–18. https://doi.org/10.1016/j.nbt.2017.12.006
https://www.textileworld.com/textile-world/fiber-world/2015/02/man-made-fibers-continue-to-grow/. Site visited 10 Jan 2019
https://www.ftc.gov/news-events/press-releases/2015/12/nordstrom-bed-bath-beyond-backcountrycom-jc-penney-pay-penalties. Site visited 10 Jan 2019
Das A, Ishtiaque SM, Singh S, Meena HC (2009) Tensile characteristics of yarns in wet condition. Indian J Fibre Text Res 34:338–344
Cox PM, Betts RA, Jones CD, Spall SA, Totterdell IJ (2000) Acceleration of global warming due to carbon-cycle feedbacks in a coupled climate model. Nature 408:184–187. Erratum ibid. (2000) 408:750. https://doi.org/10.1038/35041539, https://doi.org/10.1038/35047138
Griffith JD, Willcox S, Powers DW, Nelson R, Baxter BK (2008) Discovery of abundant cellulose microfibers encased in 250 Ma Permian halite: a macromolecular target in the search for life on other planets. Astrobiology 8(2):215–218. https://doi.org/10.1089/ast.2007.0196
https://www.plasticsinsight.com/resin-intelligence/resin-prices/polyester/. Site visited 10 Jan 2019
Durkin DP, Ye T, Choi J, Livi KJT, De Long HC, Trulove PC, Fairbrother DH, Haverhals LM, Shuai D (2018) Sustainable and scalable natural fiber welded palladium-indium catalysts for nitrate reduction. Appl Catal B 221:290–301. https://doi.org/10.1016/j.apcatb.2017.09.029
Durkin DP, Ye T, Larson E, Haverhals LM, Livi KJT, De Long HC, Trulove PC, Fairbrother DH, Shuai D (2016) Lignocellulose fiber- and welded fiber- supports for palladium based catalytic hydrogenation: a natural fiber welding application for water treatment. ACS Sustain Chem Eng 4(10):5511–5522. https://doi.org/10.1021/acssuschemeng.6b01250
Seymour S (2008) Fashionable technology, the intersection of design, fashion, science, and technology. Springer Wien, New York. https://doi.org/10.1007/978-3-211-74500-7
Sharma K (2019) Smart textile market by function (energy harvesting, sensing, thermoelectricity, luminescent, and others) and end user (healthcare, military and defense, entertainment, automotive, sport and fitness)—global opportunity analysis and industry forecast, 2014–2022. Allied market research, series: emerging and next generation technology. https://www.alliedmarketresearch.com/smart-textile-market. Site visited 10 Jan 2019
Jost K, Durkin DP, Haverhals LM, Brown EK, Langenstein M, De Long HC, Trulove PC, Gogotsi Y, Dion G (2015) Natural fiber welded electrode yarns for knittable textile supercapacitors. Adv Energy Mater 5:1401286. https://doi.org/10.1002/aenm.201401286
Durkin DP, Jost K, Brown EK, Haverhals LM, Dion G, Gogotsi Y, De Long HC, Trulove PC (2014) Knitted electrochemical capacitors via natural fiber welded electrode yarns. ECS Trans 61:17–19. https://doi.org/10.1149/06106.0017ecst
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Haverhals, L.M., Durkin, D.P., Trulove, P.C. (2020). Natural Fiber Welding. In: Shiflett, M. (eds) Commercial Applications of Ionic Liquids. Green Chemistry and Sustainable Technology. Springer, Cham. https://doi.org/10.1007/978-3-030-35245-5_9
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