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The Membrane Properties of Electroactive Polymer Films

  • Chapter
Electroactive Polymer Electrochemistry

Abstract

Electroactive polymers fall into two categories. The first group are the redox polymers, which consist of an electronically insulating polymer matrix with attached redox sites.(1–4) The PVPy/Ru matrix represented in Fig. 3.1 is a typical example. The second group are the conjugated polymers, such as polypyrrole, polyaniline, or the poly(Nsulfopropylpyrrole-co-pyrrole) represented in Fig. 3.2. These consist of extended π-electron systems from which electrons can be withdrawn (see Fig. 3.2) or into which additional electrons can be injected.(5–12) The unpaired electrons of the produced radical cations or anions are delocalized over several monomer units of the polymer chain, forming polarons that interact with one another. With increasing concentration they associate to form bipolarons, i.e., electronspin-free dimers.(13)

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  1. Fritz-Haber Institut der Max Planck Gesellschaft, D-14195, Berlin, Germany

    Karl Doblhofer

  2. A.N. Frumkin Institute of Electrochemistry, Academy of Sciences, 117071, Moscow, Russia

    Mikhail Vorotyntsev

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  1. Karl Doblhofer
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  2. Mikhail Vorotyntsev
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  1. Trinity College, University of Dublin, Dublin, Ireland

    Michael E. G. Lyons

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© 1994 Springer Science+Business Media New York

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Doblhofer, K., Vorotyntsev, M. (1994). The Membrane Properties of Electroactive Polymer Films. In: Lyons, M.E.G. (eds) Electroactive Polymer Electrochemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-5070-6_3

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  • DOI: https://doi.org/10.1007/978-1-4757-5070-6_3

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4419-3242-6

  • Online ISBN: 978-1-4757-5070-6

  • eBook Packages: Springer Book Archive

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