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Hydrogel Electrolyte

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Encyclopedia of Applied Electrochemistry
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Introduction

Rechargeable alkaline batteries such as nickel-cadmium battery and nickel-metal hydride (Ni-MH) battery include concentrated alkaline aqueous solutions as an electrolyte. The electromotive force of the Ni-MH battery is ca. 1.2 V which is a third of that of lithium ion batteries (LIBs) using nonaqueous electrolyte solutions because the former is restricted by the decomposition voltage of water. On the other hand, electrical conductivity of aqueous electrolyte solutions is more than two digits higher than that of nonaqueous solutions, which enable the rechargeable alkaline batteries to charge and discharge with high current density. Moreover, they are superior in safety to the LIBs. The rechargeable alkaline batteries have been applied to mobile electronic devices, electric power tools, hybrid electric vehicles, etc.

Due to no leakage and no freezing of electrolyte solutions and thinness and compactness of batteries, all-solid-state batteries with proton- or...

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References

  1. Inoue H, Okuda S, Higuchi E, Nohara S (2009) Inorganic hydrogel electrolyte with liquidlike ionic conductivity. Electrochem Solid-State Lett 12:A58

    CAS  Google Scholar 

  2. Chiku M, Tomita S, Higuchi E, Inoue H (2011) Preparation and characterization of organic-inorganic hybrid hydrogel electrolyte using alkaline solution. Polymers 3:1600

    CAS  Google Scholar 

  3. Fauvarquet JF, Guinot S, Bouzir N, Salmon E, Penneau JF (1995) Alkaline poly(ethylene oxide) solid polymer electrolytes. Application to nickel secondary batteries. Electrochim Acta 40:2449

    Google Scholar 

  4. Guinot S, Salmon E, Penneau JF, Fauvarque JF (1998) A new class of PEO-based SPEs: structure, conductivity and application to alkaline secondary batteries. Electrochim Acta 43:1163

    CAS  Google Scholar 

  5. Vassal N, Salmon E, Fauvarque JF (1999) Nickel/metal hydride secondary batteries using an alkaline solid polymer electrolyte. J Electrochem Soc 146:20

    CAS  Google Scholar 

  6. Vassal N, Salmon E, Fauvarque JF (2000) Electrochemical properties of an alkaline solid polymer electrolyte based on P(ECH-co-EO). Electrochim Acta 45:1527

    CAS  Google Scholar 

  7. Lewandowski A, Skorupska K, Malinska J (2000) Novel poly(vinyl alcohol)–KOH–H2O alkaline polymer electrolyte. Solid State Ionics 133:265

    CAS  Google Scholar 

  8. Yang C-C, Lin S-J (2003) Preparation of alkaline PVA-based polymer electrolytes for Ni–MH and Zn–air batteries. J Appl Electrochem 33:777

    CAS  Google Scholar 

  9. Mohamad AA, Mohamed NS, Yahya MZA, Othman R, Ramesh S, Alias Y, Arof AK (2003) Ionic conductivity studies of poly(vinyl alcohol) alkaline solid polymer electrolyte and its use in nickel–zinc cells. Solid State Ionics 156:171

    CAS  Google Scholar 

  10. Kalpana D, Renganathan NG, Pitchumani S (2006) A new class of alkaline polymer gel electrolyte for carbon aerogel supercapacitors. J Power Sources 157:621

    CAS  Google Scholar 

  11. Yuan A, Zhao J (2006) Composite alkaline polymer electrolytes and its application to nickel–metal hydride batteries. Electrochim Acta 51:2454

    CAS  Google Scholar 

  12. Sang S, Zhang J, Wu Q, Liao Y (2007) Influences of Bentonite on conductivity of composite solid alkaline polymer electrolyte PVA-Bentonite-KOH-H2O. Electrochim Acta 52:7315

    CAS  Google Scholar 

  13. Nohara S, Miura T, Iwakura C, Inoue H (2007) Electric double layer capacitor using polymer hydrogel electrolyte with 4 M H2SO4 aqueous solution. Electrochemistry 75:579

    CAS  Google Scholar 

  14. Wada H, Yoshikawa K, Furukawa N, Inoue H, Sugoh N, Iwasaki H, Iwakura C (2006) Electrochemical characteristics of new electric double layer capacitor with acidic polymer hydrogel electrolyte. J Power Sources 159:1464

    CAS  Google Scholar 

  15. Wan Y, Pepley B, Creber KAM, Tam Bui V, Halliop E (2006) Preliminary evaluation of an alkaline chitosan-based membrane fuel cell. J Power Sources 162:105

    CAS  Google Scholar 

  16. Wan Y, Creber KAM, Peppley B, Tam Bui V (2006) Chitosan-based electrolyte composite membranes: II. Mechanical properties and ionic conductivity. J Membrane Sci 284:331

    CAS  Google Scholar 

  17. Choudhury NA, Sampath S, Shukla AK (2008) Gelatin hydrogel electrolytes and their application to electrochemical supercapacitors. J Electrochem Soc 155:A74

    CAS  Google Scholar 

  18. Iwakura C, Furukawa N, Ohishi T, Sakamoto K, Nohara S, Inoue H (2001) Nickel/metal hydride cells using an alkaline polymer gel electrolyte based on potassium salt of crosslinked poly(acrylic acid). Electrochemistry 69:659

    CAS  Google Scholar 

  19. Iwakura C, Nohara S, Furukawa N, Inoue H (2002) The possible use of polymer gel electrolytes in nickel/metal hydride battery. Solid State Ionics 148:487

    CAS  Google Scholar 

  20. Iwakura K, Ikoma S, Nohara N, Furukawa H, Inoue J (2003) Charge-discharge and capacity retention characteristics of new type Ni/MH batteries using polymer hydrogel electrolyte. Electrochem Soc 150:A1623

    CAS  Google Scholar 

  21. Iwakura C, Ikoma K, Nohara S, Furukawa N, Inoe H (2005) Capacity retention characteristics of nickel/metal hydride batteries with polymer hydrogel electrolyte. Electrochem Solid-State Lett 8:A45

    CAS  Google Scholar 

  22. Nohara S, Wada H, Furukawa N, Inoue H, Morita M, Iwakura C (2003) Electrochemical characterization of new electric double layer capacitor with polymer hydrogel electrolyte. Electrochim Acta 48:749

    CAS  Google Scholar 

  23. Wada H, Nohara S, Furukawa N, Inoue H, Sugoh N, Iwasaki H, Morita M, Iwakura C (2004) Electrochemical characteristics of electric double layer capacitor using sulfonated polypropylene separator impregnated with polymer hydrogel electrolyte. Electrochim Acta 49:4871

    CAS  Google Scholar 

  24. Zhu X, Yang H, Cao Y, Ai X (2004) Preparation and electrochemical characterization of the alkaline polymer gel electrolyte polymerized from acrylic acid and KOH solution. Electrochim Acta 49:2533

    CAS  Google Scholar 

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Correspondence to Hiroshi Inoue .

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Inoue, H. (2014). Hydrogel Electrolyte. In: Kreysa, G., Ota, Ki., Savinell, R.F. (eds) Encyclopedia of Applied Electrochemistry. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-6996-5_515

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