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Thermodynamics of Metal-Mediated Assemblies of Porphyrins

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Non-Covalent Multi-Porphyrin Assemblies

Part of the book series: Structure and Bonding ((STRUCTURE,volume 121))

Abstract

An overview of the thermodynamic principles governing self-assembly in solution, with particular reference to multiporphyrin architectures, is presented. The topic is discussed in order of increasing complexity, from simple acyclic assemblies to multicyclic assemblies, by emphasizing the role played by two fundamental physicochemical quantities, namely, the stability constant of the metalloporphyrin-ligand interaction and the effective molarity, the latter being a measure of the ease of formation of a given cyclic structure or substructure. Criteria to assess cooperativity in self-assembly are also discussed. The principles are illustrated by selected examples involving metal-mediated assemblies of porphyrins in which the metal is incorporated into the porphyrin ring.

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  1. Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, Via della Ricerca Scientifica, 00133, Roma, Italy

    Gianfranco Ercolani

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  1. Gianfranco Ercolani
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Correspondence to Gianfranco Ercolani .

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Enzo Alessio

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Ercolani, G. Thermodynamics of Metal-Mediated Assemblies of Porphyrins. In: Alessio, E. (eds) Non-Covalent Multi-Porphyrin Assemblies. Structure and Bonding, vol 121. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_019

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