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Supramolecular Polymers and Networkswith Hydrogen Bonds in the Main- and Side-Chain

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Hydrogen Bonded Polymers

Part of the book series: Advances in Polymer Science ((POLYMER,volume 207))

Abstract

Control of polymeric structure is among the most important endeavors of modern macromolecularscience. In particular, tailoring the positioning and strength of intermolecular forces within macromoleculesby synthetic methods and thus gaining structural control over the final polymeric materials has becomefeasible, resulting in the field of supramolecular polymer science. Besides other intermolecularforces, hydrogen bonds are unique intermolecular forces enabling the tuning of material propertiesvia self-assembly processes over a wide range of interaction strength ranging from several kJ mol−1to several tens of kJ mol−1. The present review provides anoverview of hydrogen-bonded polymers, with a focus directed towards the type of hydrogen bondas well as their effect on the final, ordered materials. Thus, the ordering effects of single-, double-,triple-, quadruple and multiple hydrogen bonds are discussed separately. Furthermore, various architecturesas well as the use of hydrogen bonds on planar surfaces to assemble quasipolymeric structures arediscussed.

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Abbreviations

A:

hydrogen-bonding acceptor

AFM:

atomic force microscopy

AA-PDMS:

diacid telechelic poly(dimethylsiloxane)

A-PDMS:

monoacid telechelic poly(dimethylsiloxane)

ATRP:

atom transfer radical polymerization

D:

hydrogen-bonding donor

DAP:

2,6-diamino-pyridine

DBSA:

dodecyl benzenesulfonic acid

DMSO:

dimethyl sulfoxide

MDI:

methylene-4,4′-diisocyanate

NDP:

nonadecyl phenol

MMA:

methyl methacrylate

NMP:

N-methyl-morpholine

NMR:

nuclear magnetic resonance

PAA:

poly(acrylic acid)

PCL:

poly(caprolactone)

PDMS:

poly(dimethylsiloxane)

PDP:

pentadecyl phenol

PEO:

poly(ethylene oxide)

PEOx:

poly(ethyloxazoline)

PEK:

poly(ether ketone)

PI:

poly(isoprene)

PIB:

poly(isobutylene)

PIPS:

polymeric induced phase separation

PMMA:

poly(methylmethacrylate)

PPO:

poly(propylene oxide)

PS:

poly(styrene)

PSSA:

poly(styrene-4-sulfonic acid)

PS(OH):

poly(4-hydroxy-phenol)

PVAc:

poly(vinylacetate)

PVDAT:

poly(vinyldiaminotriazine)

PVP:

poly(vinylpyridine)

P4VP:

poly(4-vinylpyridine)

ROMP:

ring opening metathesis polymerisation

SAM:

self assembled monolayer

SAXS:

small angle X-ray scattering

SIMS:

dynamic secondary ion mass spectrometry

SSL:

strong segregation limit

STVPy:

styrene-co-4-vinylpyridine

STVPh:

styrene-co-4-vinylphenol

STM:

scanning tunnelling microscopy

THF:

tetrahydrofurane

TDI:

toluene-2,4-diisocyanate

WAXS:

wide angle X-ray scattering

WSL:

weak segregation limit

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Acknowledgments

The authors thank the grants FWF 14844 CHE, FWF P18740-B03 and FFG 811021 for financial support.

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  1. Institute of Applied Synthetic Chemistry, Division Macromolecular Chemistry, Vienna University of Technology, Getreidemarkt 9/163/MC, 1060, Vienna, Austria

    Wolfgang H. Binder & Ronald Zirbs

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  1. Wolfgang H. Binder
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Correspondence to Wolfgang H. Binder .

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Binder, W.H., Zirbs, R. (2006). Supramolecular Polymers and Networkswith Hydrogen Bonds in the Main- and Side-Chain. In: Binder, W. (eds) Hydrogen Bonded Polymers. Advances in Polymer Science, vol 207. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2006_109

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