Skip to main content

Modelling Chemical and Physical Processes of Hg Compounds in the Marine Boundary Layer

  • Chapter
Dynamics of Mercury Pollution on Regional and Global Scales:

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Ariya, P.A., Khalizov, A., Gidas, A. Reaction of gaseous mercury with atomic and molecular halogens: kinetics, products studies, and atmospheric implications, J. Phys. Chem. A, 106, 7310–7320, 2002.

    Article  CAS  Google Scholar 

  • ATMET, Atmospheric, Meteorological and Environmental Technologies, 2004 http://atmet.com.

    Google Scholar 

  • Barrie, L.A., Bottenheim, J.W., Schnell, R.C., Crutzen, P.J., Rasmussen, R.A. Ozone destruction and photochemical reactions at polar sunrise in the lower Arctic atmosphere, Nature, 334, 138–141, 1988.

    Article  CAS  Google Scholar 

  • Barrie, L., Platt, U. Arctic tropospheric chemistry: an overview, Tellus, 49B, 450–454, 1997.

    CAS  Google Scholar 

  • Bauer, D., D’Ottone, L., Campuzano-Jost, P., Hynes, A.J. Gas phase elemental mercury: a comparison of LIF techniques and study of the kinetics of reaction with the hydroxyl radical, J. Photochem. Photobiol. A, 157, 247–256, 2003.

    Article  CAS  Google Scholar 

  • Bottenheim J.W., Gallant A.C., Brice K.A. Measurements of NOy species and O3 at 82° N latitude, Geophys. Res. Lett., 13, 113–116, 1986.

    CAS  Google Scholar 

  • Clever, H.L., Johnson, S.A., Derrick, M.E. The solubility of Mercury and Some Sparingly Soluble Mercury Salts in Water and Aqueous Electrolyte Solutions. J. Phys. Chem. Refer. Data, 14, 631–680, 1985.

    CAS  Google Scholar 

  • Fan, S-M. Jacob, D.J. Surface ozone depletion in Arctic spring sustained by bromine reactions on aerosols, Nature, 359, 522–524, 1992.

    Article  CAS  Google Scholar 

  • Foster, K.L., Plastridge, R.A., Bottenheim, J.A., Shepson, P.B., Finlayson-Pitts, B.J., Spicer, C.W. The role of Br2 and BrCl in surface ozone destruction at polar sunrise, Science, 291, 471–474, 2001.

    Article  CAS  Google Scholar 

  • GÃ¥dfeldt, K., Jonsson, M. Is bimolecular reduction of divalent mercury complexes possible in aqueous systems of environmental importance? J. Phys. Chem. A, 107, 4478–4482, 2003.

    Article  CAS  Google Scholar 

  • Hall, B., Bloom N., Report to EPRI, Palo Alto, CA, USA, 1993.

    Google Scholar 

  • Hall, B. The phase oxidation of elemental mercury by ozone. Water, Air Soil Pollut., 80, 301–315, 1995.

    Article  CAS  Google Scholar 

  • Hedgecock, I.M., Pirrone, N. Mercury photochemistry in the marine boundary layer modeling studies suggest the in situ production of reactive gas phase mercury, Atmos. Environ., 35, 3055–3062, 2001.

    Article  CAS  Google Scholar 

  • Hedgecock, I.M., Pirrone, N., Sprovieri, F., Pesenti, E. Reactive gaseous mercury in the marine boundary layer: Modeling and experimental evidence of its formation in the Mediterranean region, Atmos. Environ., 37, S41–49, 2003.

    Article  CAS  Google Scholar 

  • Hedgecock, I.M., Pirrone, N. Chasing Quicksilver: Modeling the Atmospheric Lifetime of Hg 0(g) in the Marine Boundary Layer at Various Latitudes. Environ. Sci. Technol., 38, 69–76, DOI: 10.1021/es034623z, 2004.

    Article  CAS  Google Scholar 

  • Kallos, G., Kotroni, V., Lagouvardos K., Papadopoulos, A. On the long-range transport of air pollutants from Europe to Africa, Geophys. Res. Lett., 25, 619–622, 1998.

    Article  CAS  Google Scholar 

  • Laurier, F.J.G., Mason, R.P., Whalin, L., Kato, S. Reactive gaseous mercury formation in the North Pacific Ocean’s marine boundary layer: A potential role of halogen chemistry, J. Geophys. Res., 108, 4529. doi:l0.1029/2003JD003625, 2003.

    Article  CAS  Google Scholar 

  • Lelieveld, J., Berresheim, H., Borrmann, S., Crutzen, P.J., Dentener, F.J., Fischer, H., Feichter, J., Flatau, P.J., Heland, J., Holzinger, R., Korrmann, R., Lawrence, M.G., Levin, Z., Markowicz, K.M., Mihalopoulos, N., Minikin, A., Ramanathan, V., De Reus, M., Roelofs, G.J., Scheeren, H.A., Sciare, J., Schlager, H., Schultz, M., Siegmund, P., Steil, B., Stephanou, E.G., Stier, P., Traub, M., Warneke, C., Williams, J., Ziereis, H. Global air pollution crossroads over the Mediterranean, Science, 298, 794–799, 2002.

    Article  CAS  Google Scholar 

  • Lin, C-J., Pehkonen, S.O. Aqueous Free Radical Chemistry of Mercury in the Presence of Iron Oxides and Ambient Aerosol. Atmos. Environ., 31, 4125–4137, 1997.

    Article  CAS  Google Scholar 

  • Lin, C-J., Pehkonen, S.O. Two-Phase Model of Mercury Chemistry in the Atmosphere. Atmos. Environ., 32, 2543–2558, 1998.

    Article  CAS  Google Scholar 

  • Lin, C-J., Pehkonen, S.O. Aqueous Phase Reactions of Mercury with Free Radicals and Chlorine: Implications for Atmospheric Mercury Chemistry. Chemosphere, 38, 1253–1263, 1999.

    Article  CAS  Google Scholar 

  • Mason, R.P., Lawson, N.M., Sheu, G.-R. Mercury in the Atlantic Ocean: factors controlling air-sea exchange of mercury and its distribution in the upper waters. Deep-sea Res. II, 48, 2829–2853, 2001.

    Article  CAS  Google Scholar 

  • Mason, R.P., G.-R. Sheu, The role of the ocean in the global mercury cycle, Global Biogeochem. Cyc., 16, 1093. doi:10.1029/2001GB001440, 2002.

    Article  CAS  Google Scholar 

  • Munthe J. The aqueous oxidation of elemental mercury by ozone. Atmos. Environ., 26A, 1461–1468, 1992.

    CAS  Google Scholar 

  • Nagao, I., Matsumoto, K., Tanaka, H. Sunrise ozone destruction found in the sub-tropical marine boundary layer, Geophys. Res. Lett., 26, 3377–3380, 1999.

    Article  CAS  Google Scholar 

  • Nolle, M., Ellul, R., Heinrich, G., Gusten, H., A Long term of Background Ozone Concentrations in the Central Mediterranean — Diurnal and Seasonal Variations on the Island of Gozo, Atmos. Environ., 36, 1391–1402, 2002.

    Article  CAS  Google Scholar 

  • O’Dowd, C., Jimenez, J.L., Bahreini, R., Flagan, R.C., Seinfeld, J.H., Hameri, K., Pirjola, L, Kulmala, M., Jennings, S.G., Hoffmann, T. Marine aerosol formation from biogenic iodine emissions, Nature, 417, 632–636, 2002.

    Article  CAS  Google Scholar 

  • Pal, B., Ariya, P.A. Studies of ozone initiated reactions of gaseous mercury: kinetics, product studies, and atmospheric implications, Phys. Chem. Chem. Phys., 6, 572–579, 2004.

    Article  CAS  Google Scholar 

  • Pehkonen, S.O., Lin, C-J. Aqueous Photochemistry of Mercury with Organic Acids. J. A&WM Assoc., 48, 144–150, 1997.

    Google Scholar 

  • Pirrone, N., Hedgecock, I.M., Forlano, L., The role of the ambient aerosol in the atmospheric processing of semi-volatile contaminants: A parametrised numerical model (GASPAR), J. Geophys. Res., 105, 9773–9790, 2000.

    Article  CAS  Google Scholar 

  • Pleijel, K., Munthe, J. Modelling the Atmospheric Mercury Cycle — Chemistry in Fog Droplets. Atmos. Environ., 29, 1441–1457, 1995.

    Article  CAS  Google Scholar 

  • Sander, R., Keene, W.C., Pszenny, A.A.P., Arimoto, R., Ayers, G.P., Baboukas, E., Cainey, J.M., Crutzen, P.J., Duce, R.A., Hönninger, G., Huebert, B.J., Maenhaut, W., Mihalopoulos, N., Turekian, V.C., Van Dingenen, R. Inorganic bromine in the marine boundary layer: a critical review. Atmos. Chem. Phys. Discuss., 3, 3050, 2003.

    Google Scholar 

  • Sander, R. Modeling atmospheric chemistry: Interactions between gas-phase species and liquid cloud/aerosol particles. Sum. Geophys., 20, 1–31, 1999.

    Article  Google Scholar 

  • Sander, R., Cruzten, P.J. Model study indicating halogen activation and ozone destruction in polluted air masses transported to the sea, J. Geophys. Res., 101, 9121–9138, 1996.

    Article  CAS  Google Scholar 

  • Schroeder, W.H., Anlauf, KG., Barrie, L.A., Lu, J.Y., Steffen, A., Schneeberger, D.R., Berg, T Artic springtime depletion of mercury, Nature, 394, 331–333, 1998.

    Article  CAS  Google Scholar 

  • Schroeder, W. H., Munthe, J., Atmospheric Mercury — an overview, Atmos. Environ., 32, 809–822, 1998.

    Article  CAS  Google Scholar 

  • Seibert, P., Beyrich, F., Gryning, S-E., Joffre, S., Rasmussen, A., Tercier, P. Review of operational methods for the determination of the mixing height, Atmos. Environ., 34, 1001–1027, 2000.

    Article  CAS  Google Scholar 

  • Seinfield, J. H., Pandis, S. N. Atmospheric Chemistry and Physics — From Air Pollution to Climate Change, John Wiley and Sons, Inc., New York., 1998.

    Google Scholar 

  • Sommar, J., Hallquist, M., Ljungstrom, E., Lindqvist, O. On the gas phase reactions between volatile biogenic mercury species and the nitrate radical, J. Atmos. Chem., 27, 233–247, 1997.

    Article  CAS  Google Scholar 

  • Sommar, J., GÃ¥rdfeldt, K., Strömberg, D., Feng, X. A kinetic study of the gas-phase reaction between the hydroxyl radical and atomic mercury, Atmos. Environ., 37, 3049–3054, 2001.

    Article  Google Scholar 

  • Sprovieri, F., Pirrone, N., GÃ¥rfeldt, K., Sommar, J. Mercury speciation in the marine boundary layer along a 6000 km cruise path around the Mediterranean Sea, Atmos. Environ., 37, S63–71, 2003.

    Article  CAS  Google Scholar 

  • Tokos, J. J.S., Hall, B., Calhoun, J. A., Prestbo, E. M. Homogeneous gas phase reaction of Hg0 with H2O2, O3, CH3I, and (CH3)2S: implications for atmospheric Hg cycling, Atmos. Environ., 32, 823–827, 1998.

    Article  CAS  Google Scholar 

  • Toyota K., Takahashi, M., Akimoto, H., Modeling multiphase halogen chemistry in the marine boundary layer with size segregated aerosol module: Implication for quasi-size dependent approach, Geophys. Res. Lett., 28, 2899–2902, 2001.

    Article  CAS  Google Scholar 

  • Toyota K., Kanaya, Y., Takahashi, M., Akimoto, H., A box model study on photochemical interactions between VOCs and reactive halogen species in the marine boundary layer, Atmos. Chem. Phys. Discuss., 3, 4549–4632, 2003.

    Article  Google Scholar 

  • Van Loon, L. L., Mader, E. A., Scott, S. L. Sulfite Stabilization and Reduction of the Aqueous Mercuric Ion: Kinetic Determination of Sequential Formation Constants, J. Phys. Chem. A., 105, 3190–3195, 2001.

    Article  CAS  Google Scholar 

  • Van Loon, L. L., Mader, E. A., Scott, S. L. Reduction of the Aqueous Mercuric Ion by Sulfite: UV Spectrum of HgSO3 and Its Intramolecular Redox Reaction, J. Phys. Chem. A., 104, 1621–1626, 2000.

    Article  CAS  Google Scholar 

  • Vogt, R., Crutzen, P. J., Sander, R. A mechanism for halogen release from sea-salt aerosol in the remote marine boundary layer, Nature, 383, 327–330, 1996.

    Article  CAS  Google Scholar 

  • W:angberg, I., Munthe, J., Pirrone, N., Iverfeldt, Ã…., Bahlman, E., Costa, P., Ebinghaus, R., Feng, X., Ferrara, R., GÃ¥rdfeldt, K., Kock, H., Lanzillotta, E., Mamane, Y., Mas, F., Melamed, E., Osnat, Y., Prestbo, E., Sommar, J., Schmolke, S., Spain, G., Sprovieri, F., Tuncel, G. Atmospheric mercury distribution in Northern Europe and in the Mediterranean region, Atmos. Environ., 35, 3019–3025, 2001.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2005 Springer Science+Business Media Inc.

About this chapter

Cite this chapter

Hedgecock, I.M., Pirrone, N. (2005). Modelling Chemical and Physical Processes of Hg Compounds in the Marine Boundary Layer. In: Pirrone, N., Mahaffey, K.R. (eds) Dynamics of Mercury Pollution on Regional and Global Scales:. Springer, Boston, MA. https://doi.org/10.1007/0-387-24494-8_13

Download citation

Publish with us

Policies and ethics