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A Revision of the Al-rich Region of the Sm-Al Phase Diagram: The Sm3Al11 Phase

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Phase equilibria in the Al-rich region of the Sm-Al binary system has been revised and updated: it has been confirmed that Sm3Al11 is a congruently melting phase which, on cooling, undergoes catatectic decomposition Sm3Al11 ↔ liquid + SmAl3.

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References

  1. Cacciamani G., Ferro R. (2001) Thermodynamic Modeling of Some Aluminium-rare Earth Binary Systems: Al-La, Al-Ce and Al-Nd. Calphad 25(4):583–597 in English

    Article  Google Scholar 

  2. K.A. Gschneidner Jr. and F.W. Calderwood, The Al-RE (Aluminium-Rare Earth) Systems, Bullettin of Alloy Phase Diagrams, 1988, 9(6), p. 658-668, in English

  3. Buschow K.H.J., Van Vucht J.H.N. (1967) Systematic Arrangement of the Binary Rare-Earth-Aluminium systems. Philips Res. Reports, 22:233–245 in English

    Google Scholar 

  4. Casteels F. (1967) The Aluminium-rich Parts of the Aluminium-Samarium and Aluminium-Dysprosium Systems. J. Less-Common Metals 12:210–220 in English

    Article  Google Scholar 

  5. V.I. Kononenko and S.V. Golubev, Phase Diagrams of the Binary Systems of Al with La, Ce, Pr, Nd, Sm, Eu, Yb, Sc and Y, Izv. Akad. Nauk SSSR, Met., 1990, 2, p. 197-199, in Russian

  6. Saccone A., Cacciamani , Macciò D., Borzone G., Ferro R. (1998) Contribution to the Study of the Alloys and Intermetallic Compounds of Aluminium with the Rare-earth Metals. Intermetallics 6:201–215 in English

    Article  Google Scholar 

  7. Borzone G., Cardinale A., Saccone A., Ferro R. (1995) Enthalpies of Formation of Solid Sm-Al Alloys. J. Alloys Compounds 220:122-125 in English

    Article  Google Scholar 

  8. G. Borzone, R.Raggio, S. Delsante, and R. Ferro, European Congress and Exhibition on Advanced Materials and Processes-EUROMAT 2003, Losanna, (Svizzera) 1–5 September 2003, in English

  9. S. Delsante, “Constitutional, Thermochemical and Electrochemical Properties of Multicomponent Alloys Containing Rare Earths and Transition Metals,” Ph.D. Thesis, Genova University, 2006, in English

  10. W. Parrish and A.J.C. Wilson, International Tables X-Ray Crystallography, Vol. 2, J.S. Kasper and K. Lonsdale, Eds., The Kynoch Press, Birmingham, UK, 1959, in English

  11. Ferro R., Saccone A., Delfino S., Cardinale A.M., Macciò D. (1996) Inverse Melting in Binary Systems: Morphology and Microscopy of Catatectic Alloys. Metall. Mater. Trans 27B:979–986 in English

    Article  Google Scholar 

  12. Buschow K.H.J., Van Vucht J.H.N. (1965) On the Intermediate Phases in the System Samarium-Aluminium. Philips Res. Reports 20:15–22 in English

    Google Scholar 

  13. Van Vucht J.H.N., Buschow K.H.J. (1964) On the Binary Aluminium-Rich Compounds of the Rare-Earth Elements. Philips Res. Reports, 19:319–322 in English

    Google Scholar 

  14. Villars P., Calvert L.D. (1991) Pearson’s Handbook of Crystallographic Data for Intermetallics Phases. ASM International, Materials Park, OH, USA in English

    Google Scholar 

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Acknowledgments

The Italian Ministero dell’Istruzione dell’Università e della Ricerca is acknowledged with thanks for the financial support given to the framework of a National Research Project entitled “Caratterizzazione chimica fisica di composti intermetallici in forma di bulk ed in forma di film.” The INSTM (Italian Inter-University Consortium on Materials Science and Technology) is acknowledged with thanks for the co-financed Doctorate grant.

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Delsante, S., Raggio, R., Borzone, G. et al. A Revision of the Al-rich Region of the Sm-Al Phase Diagram: The Sm3Al11 Phase. J Phs Eqil and Diff 28, 240–242 (2007). https://doi.org/10.1007/s11669-007-9082-1

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  • DOI: https://doi.org/10.1007/s11669-007-9082-1

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