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Molecular Wires

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Molecular Wires and Electronics

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 257))

Abstract

Molecular wires are compounds that are proposed to be used in molecular electronic and optoelectronic devices to replace the metal and silicon-based wires in semiconductor devices. We review the field, including organic molecular wires such as oligo(2,5-thiophene ethynylene)s, oligo(1,4-phenylene ethynylene)s, oligo(1,4-phenylene vinylene)s, aromatic ladder oligomers, oligophenylenes, polyphenylenes, acetylene oligomers, carbon nanotubes, and organometallic molecular wires. We briefly review the measurement of conduction in molecular wires and conclude that fully conjugated organic aromatic molecular wires are the best candidates for introduction into new electronic devices as replacements for the Al or Cu wiring presently used in logic and memory devices.

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Abbreviations

cAFM:

conducting atomic force microscopy

CNTFETs:

carbon nanotube field effect transistors

CV:

cyclic voltammetry

DMSO:

dimethylsulfoxide

NDR:

negative differential resistance

OLED:

organic light emitting diodes

OTEs:

oligo(2-5-thiophene ethynylene)s

OPEs:

oligo(1,4-phenylene ethynylene)s

OPVs:

oligo(1,4-phenylene vinylene)s

SAM:

self-assembled monolayer

STM:

scanning tunneling microscopy

SWE:

single wavelength ellipsometry

SWNT:

single-walled nanotube

Terpy:

terpyridine

XPS:

X-ray photoelectron spectroscopy

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Authors and Affiliations

  1. Chemistry Department, Rice University, MS-60, 6100 Main St., 77005, Houston, Texas, USA

    Dustin K. James

  2. Chemistry Dept. and Center for Nanoscale Science and Technology, Rice University, MS-222, 6100 Main St., 77005, Houston, Texas, USA

    James M. Tour

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  1. Dustin K. James
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  2. James M. Tour
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Correspondence to Dustin K. James .

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© 2005 Springer-Verlag Berlin Heidelberg

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James, D.K., Tour, J.M. (2005). Molecular Wires. In: Molecular Wires and Electronics. Topics in Current Chemistry, vol 257. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b136066

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