Summary
The equilibrium geometry and barrier to pyramidal inversion of triisopropylamine, N(CH(CH3)2)3, is computed at SCF level of theory. For comparison, results for ammonia NH3 (including a near HF calculation), trimethylamine N(CH3)3 and the three analogous phosphine compounds PH3, P(CH3)3 and P(CH(CH3)2)3 are presented as well.
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Kölmel, C., Ochsenfeld, C. & Ahlrichs, R. Anab initio investigation of structure and inversion barrier of triisopropylamine and related amines and phosphines. Theoret. Chim. Acta 82, 271–284 (1992). https://doi.org/10.1007/BF01113258
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DOI: https://doi.org/10.1007/BF01113258