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Preparation of rhodium niobate compound by chemical mixing methods: Effect of preparation method on SMSI behavior of RhNbO4/SiO2 catalysts

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Abstract

Rhodium niobate was prepared as a complex oxide supported on silica via tetra-alkyl ammonium and citrate complexation. After calcination at 750 °C, the complex oxide was formed essentially in the monophasic columbite structure as determined by means of XRD. The two silica-supported RhNbO4 catalysts were tested for their activity toward ethane hydrogenolysis, and a large difference in SMSI behavior was observed for the two preparations.

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References

  1. Z. Hu, H. Nakamura, K. Kunimori, H. Asano and T. Uchijima, J. Catal. 112 (1988) 478.

    Google Scholar 

  2. Z. Hu, H. Nakamura, K. Kunimori, Y. Yokoyama, H. Asano, M. Soma and T. Uchijima, J. Catal. 119 (1989) 33.

    Google Scholar 

  3. A. Ueno, H. Suzuki and Y. Kotera, J. Chem. Soc., Faraday Trans. I, 79 (1983) 127.

    Google Scholar 

  4. S. Niwa, F. Mizukarni, M. Kuno, K. Takeshita, H. Nakamura, T. Tsuchiya, K. Shimizu and J. Imamura, J. Mol. Catal. 34 (1986) 247.

    Google Scholar 

  5. Y.G. Yin, K. Kunimori and T. Uchijima, to be submitted.

  6. S. Si Larbi, D. Bodiot and B. Spinner, Rev. Chim. Miner. 13 (1976) 497.

    Google Scholar 

  7. C. Marcilly, P. Courtry and B. Delmon, J. Amer. Cer. Soc. 53 (1970) 56.

    Google Scholar 

  8. H.M. Zhang, Y. Teraoka and N. Yamazoe, Appl. Catal. 41 (1988) 137.

    Google Scholar 

  9. J.I. Di Cosimo and C.R. Apesteguia, J. Catal. 116 (1989) 71.

    Google Scholar 

  10. Shokubai (Catalyst), Vol. 29, No. 7 (1987) p. 5.

  11. Z. Hu, H. Nakamura, K. Kunimori and T. Uchijima, Catal. Lett. 1 (1988) 271.

    Google Scholar 

  12. G.L. Haller and D.E. Resasco, in:Advances in Catalysis, eds. D.D. Eley, H. Pines and P.B. Weisz, Vol. 36 (Academic Press, New York, 1989) p. 173.

    Google Scholar 

  13. K. Asakura, Y. Iwasawa and H. Kuroda, J. Chem. Soc., Faraday Trans. I, 84 (1989) 1329.

    Google Scholar 

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Authors and Affiliations

  1. Beijing Institute of Chemical Fiber Technology, Beijing, China

    Y. G. Yin (Visiting professor)

  2. Institute of Materials Science, University of Tsukuba, Tsukuba, 305, Ibaraki, Japan

    Y. G. Yin (Visiting professor), T. Wakasugi, H. Shindo, S. Ito, K. Kunimori & T. Uchijima

Authors
  1. Y. G. Yin
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  2. T. Wakasugi
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  3. H. Shindo
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  4. S. Ito
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  5. K. Kunimori
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  6. T. Uchijima
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Yin, Y.G., Wakasugi, T., Shindo, H. et al. Preparation of rhodium niobate compound by chemical mixing methods: Effect of preparation method on SMSI behavior of RhNbO4/SiO2 catalysts. Catal Lett 9, 43–46 (1991). https://doi.org/10.1007/BF00769079

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  • DOI: https://doi.org/10.1007/BF00769079

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