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Synthesis, structure and characterization of binuclear silver(I) complexes

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Summary

Two binuclear AgI complexes, [{Ag(dppp)}2](NO3)2 (1) and [{Ag(dppb)}2(NO3)]2 (2) (dppp = Ph2P(CH2)3PPh2, dppb = Ph2P(CH2)4PPh2], were synthesized and characterized by elemental analysis, t.g., i.r. and 31P-n.m.r. spectra. Single crystals of complex (2) were obtained from MeOH-CHCl3. The X-ray crystal structure shows that the dppb ligand is bidentate, with two ligands bridging two metal ions to form a centrosymmetric dimer.

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Authors and Affiliations

  1. Henan Institute of Chemistry, 450003, Zhengzhou, P.R. China

    Yang Ruina, Hou Yimin, Xue Baoyu, Wang Dongmei & Jin Douman

Authors
  1. Yang Ruina
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  2. Hou Yimin
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  3. Xue Baoyu
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  4. Wang Dongmei
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  5. Jin Douman
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Ruina, Y., Yimin, H., Baoyu, X. et al. Synthesis, structure and characterization of binuclear silver(I) complexes. Transition Met Chem 21, 28–30 (1996). https://doi.org/10.1007/BF00166008

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  • DOI: https://doi.org/10.1007/BF00166008

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