Definition
Supramolecular polymers are defined as polymers formed by non-covalent bonds. Non-covalent bonds include hydrogen bonds, coordination bonds, donor-acceptor bonds, and host-guest interactions.
Supramolecular Polymers (Definition)
Supramolecular polymers are defined as polymers linked by intermolecular non-covalent interactions among molecules. Intermolecular interactions are involved in hydrogen bonds, metal-ligand interactions, donor-acceptor bonds, and host-guest interaction. Here in this chapter, supramolecular polymers formed by host-guest interactions are mainly focused on. (Supramolecular polymers involved in cyclodextrins are described in detail in another chapter, so the description of such supramolecular polymers is limited to the overview.)
The term “supramolecular polymers” was first proposed by J. Lehn in his book on Supramolecular Chemistry [1].
There are various types of supramolecular polymers...
References
Lehn J-M (1995) Supramolecular chemistry. VCH, Weinheim
Ashton PR, Baxter I, Cantrill SJ, Fyfe MCT, Glink PT, Stoddart JF, White AJP, Williams DJ (1998) Supramolecular daisy chains. Angew Chem Int Ed 37:1294–1297
Ashton PR, Parsons IW, Raymo FM, Stoddart JF, White AJP, Williams DJ, Wolf R (1998) Self-assembling supramolecular daisy chains. Angew Chem Int Ed 37:1913–1916
Yamaguchi N, Gibson HW (1999) Formation of supramolecular polymers from homoditopic molecules containing secondary ammonium ions and crown ether moieties. Angew Chem Int Ed 38:143–147
Yamaguchi N, Gibson HW (1999) Stabilities of cooperatively formed cyclic pseudorotaxane dimers. Chem Commun 9:789–790
Gibson HW, Yamaguchi N, Jones JW (2003) Supramolecular pseudorotaxane polymers from complementary pairs of homoditopic molecules. J Am Chem Soc 125:3522–3533
Jr Price T, Gibson HW (2012) Crown ether-based polymeric rotaxanes. In: Harada A (ed) Supramolecular polymer chemistry. Wiley-VCH, Weinheim
Guo DS, Liu Y (2012) Calixarene-based supramolecular polymerization in solution. Chem Soc Rev 41:5907–5921
Tancini F, Dalcanale E (2012) Polymerization with ditopic cavitand monomers. In: Harada A (ed) Supramolecular polymer chemistry. Wiley-VCH, Weinheim
Lee JW, Samal S, Selvapalam N, Kim H-J, Kim K (2003) Cucurbituril homologues and derivatives: new opportunities in supramolecular chemistry. Acc Chem Res 36:621–630
Huang F, Scherman OA (2012) Supramolecular polymers. Chem Soc Rev 41:5879–5880
Rauwald U, Scherman OA (2008) Supramolecular block copolymers with cucurbit[8]uril in water. Angew Chem Int Ed 47:3950–3953
Kim K, Ko YH, Selvapalam N (2013) Cucurbiturils: chemistry, supramolecular chemistry and applications. Imperial College Press, London
Regen N, Isaacs L (2009) Toward supramolecular polymers incorporating double cavity cucurbituril hosts. Tetrahedron 65:7249–7258
Kim K (2002) Mechanically interlocked molecules incorporating cucurbituril and their supramolecular assemblies. Chem Soc Rev 31:96–107
Appel EA, Biedermann F, Rauwald U, Jones ST, Zayed JM, Scherman OA (2010) Supramolecular cross-linked networks via host − guest complexation with Cucurbit[8]uril. J Am Chem Soc 132:14251–14260
Ogoshi T, Kanai S, Fujinami S, Yamagishi T, Nakamoto Y (2008) para-bridged symmetrical Pillar[5]arenes: their Lewis acid-catalyzed synthesis and host-guest property. J Am Chem Soc 130:5022–5023
Ogoshi T, Yamagishi T (2013) Pillararenes: versatile synthetic receptors for supramolecular chemistry. Eur J Org Chem 2013:2961–2975. doi:10.1002/ejoc.201300079
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2013 Springer-Verlag Berlin Heidelberg
About this entry
Cite this entry
Harada, A. (2013). Supramolecular Polymers (Host-Guest Interactions). In: Kobayashi, S., Müllen, K. (eds) Encyclopedia of Polymeric Nanomaterials. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-36199-9_54-1
Download citation
DOI: https://doi.org/10.1007/978-3-642-36199-9_54-1
Received:
Accepted:
Published:
Publisher Name: Springer, Berlin, Heidelberg
Online ISBN: 978-3-642-36199-9
eBook Packages: Springer Reference Chemistry and Mat. ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics