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Standard molar enthalpy of sublimation of crystalline 3-pyridinecarboxylic acid

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Cited by (13)

  • Structure and energetics correlations in some chlorohydroxypyridines

    2013, Journal of Chemical Thermodynamics
    Citation Excerpt :

    The present work is part of a systematic thermochemical study of substituted pyridines performed in the Thermochemistry group of Porto for nearly two decades. Over the years different substituted pyridines have been studied experimentally and/or computationally in order to better understand the relation between structure and energetics in this family of compounds: mono- and dihydroxypyridines [1–3], mono-, di- and trichloropyridines [4,5], mono- and dibromopyridines [6], trimethylpyridines [7], bipyridines [8,9], mono- and dicarboxylic acid pyridines [10–12], mono- and dicarboxylic acid methyl ester pyridines [12,13], monophenylpyridines [14], monocarboxamide pyridines [15], monoethylpyridines [16], monoacetylpyridines [17], mono-, di- and tri-tert-butylpyridines [18] and mono- and dimethoxypydines [19]. With the present work we intend to enlarge the thermochemical database for disubstituted pyridines by the experimental determination of the standard molar enthalpies of formation of some chlorohydroxypyridines and to use computational chemistry in the understanding of the relation between structure and energetics and to obtain reliable estimates of the enthalpies of formation for those isomers that were not experimentally studied.

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