Regular ArticleThe Rare Earth CarbidesR4C5withR=Y, Gd, Tb, Dy, and Ho
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Design of the rare-earth-containing materials based on the micro-alloying phase equilibria, phase diagrams and phase transformations
2023, Journal of Materials Science and TechnologyAlloy Systems and Compounds Containing Rare Earth Metals and Carbon
2017, Handbook on the Physics and Chemistry of Rare EarthsCitation Excerpt :Temperature of βHoCx ↔ αHo2Cx transformation needs additional investigation. Ho4C5 compound was synthesized only after long-term annealing of the as-cast alloys with the atomic ratio Ho:C = 48:52 for 40 days at 1050°C [13]. In the alloy with slightly off the ideal composition 4:5, a bcc Ho3C as the impurity phase was detected.
Stability and elastic properties of Y-C binary compounds investigated by first principles calculations
2014, Journal of Alloys and CompoundsNew ternary rare-earth metal boride carbides R<inf>15</inf>B <inf>4</inf>C<inf>14</inf> (R=Y, GdLu) containing BC<inf>2</inf> units: Crystal and electronic structures, magnetic properties
2010, Journal of Solid State ChemistryCitation Excerpt :At the metal rich side defect NaCl-type carbides are known with compositions around R3C, R2C and R4C5. Single carbon atoms are located in octahedral lanthanoid voids in R3C, in R2C, and R4C5 structures, single carbon atoms coexist with C2 pairs [1,2]. Several compounds with higher carbon contents have been previously reported with the approximate composition R15C19 [3–8], and they were later established for R=Sc, Ho–Lu as the Sc3C4-type structure [9] with three different kinds of carbon species: isolated carbon atoms, C2 and C3 units, respectively.
High-pressure synthesis of dysprosium carbides
2023, Frontiers in Chemistry
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