Abstract
We present a detailed investigation of the surface electronic structure of solid in connection with its electronic transport properties. We find that the conductivity is extremely sensitive to the K concentration of the surface layer, and that the best-conducting samples with the highest superconducting transition temperatures have surfaces with the highest density of states at the Fermi level as measured by photoemission. The ions at the surface have, however, a valence that deviates appreciably from the bulk value, namely or even depending on the preparation procedure. We attribute this as being the result of an electronic rather than an atomic surface reconstruction to avoid the divergence of the electrostatic potential associated with the polar (111) surface termination of We argue that such a mixed-valence surface should always be a metal, irrespective of whether the bulk is a metal or a Mott-Hubbard insulator.
- Received 19 April 2000
DOI:https://doi.org/10.1103/PhysRevB.62.16046
©2000 American Physical Society