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Photo-induced interfacial electron transfer from CdSe quantum dots to surface-bound p-benzoquinone and anthraquinone

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Abstract

Here we report transient spectral red-shift and transient absorption enhancement of p-benzoquinone radical in the presence of CdSe quantum dots after 355 nm pulse laser excitation. The spectral shift was caused by surface-bound p-benzoquinone molecules while the transient absorption increase was due to interfacial electron transfer from CdSe quantum dots to p-benzoquinone molecules. In contrast, spectral shift and absorption increase were much less significant for anthraquinone in the presence of CdSe quantum dots due to their weak adsorption abilities.

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Correspondence to Guozhong Wu.

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Long, D., Wu, G., Wang, W. et al. Photo-induced interfacial electron transfer from CdSe quantum dots to surface-bound p-benzoquinone and anthraquinone. Res Chem Intermed 33, 655–661 (2007). https://doi.org/10.1163/156856707781749937

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  • DOI: https://doi.org/10.1163/156856707781749937

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