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Indirect electrochemical oxidation of aniline in acid electrolyte with active oxygen species

  • Applied Electrochemistry and Metal Corrosion Protection
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Abstract

Kinetics and selectivity of the aniline oxidation on a boron-doped diamond electrode and lead dioxide anode (Pb/PbO2) in an acid electrolyte were studied under various generation conditions of active oxygen species. The resulting kinetic dependences can be described by a pseudo-first-order equation. The apparent rate constants of the process were determined for two electrolysis modes: direct anodic oxidation and oxidation with addition of hydrogen peroxide. UV spectroscopy was used to determine that the aniline destruction process occurs via formation of a number of intermediate products (benzoquinone, carboxylic acids). It was shown that the aniline destruction process can occur with a rather high efficiency (~80–90%) on the electrode types under study.

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Authors and Affiliations

  1. Federal Research Center Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk, 660036, Russia

    G. V. Kornienko, T. A. Kenova, V. L. Kornienko & N. G. Maksimov

  2. Siberian State Aerospace University named after M.F. Reshetnev, pr. imeni gazety Krasnoyarskii Rabochii 31, Krasnoyarsk, 660037, Russia

    G. V. Kornienko & M. Yu. Balhareva

Authors
  1. G. V. Kornienko
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  2. T. A. Kenova
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  3. V. L. Kornienko
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  4. N. G. Maksimov
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  5. M. Yu. Balhareva
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Corresponding author

Correspondence to V. L. Kornienko.

Additional information

Original Russian Text © G.V. Kornienko, T.A. Kenova, V.L. Kornienko, N.G. Maksimov, M.Yu. Balhareva, 2016, published in Zhurnal Prikladnoi Khimii, 2016, Vol. 89, No. 10, pp. 1290−1297.

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Kornienko, G.V., Kenova, T.A., Kornienko, V.L. et al. Indirect electrochemical oxidation of aniline in acid electrolyte with active oxygen species. Russ J Appl Chem 89, 1612–1618 (2016). https://doi.org/10.1134/S1070427216100086

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  • DOI: https://doi.org/10.1134/S1070427216100086

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