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Electrochemical synthesis of 1-isonicotinoyl-2-isopropylhydrazine on stationary solid electrodes

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Abstract

The possibility of preparing isonicotinoylisopropylhydrazine by electrochemical reduction of the corresponding hydrazone on stationary solid electrodes (titanium, zirconium, nickel, iron, iron-based alloys) was demonstrated. The electrolysis is performed in the cathodic space of the electrolyzer on solid cathodes in aqueous-alcoholic solutions, with glassy carbon used as anode. The hydrazone electroreduction is performed at the cathodic current density of 0.1–0.5 A dm–2 in the temperature interval 40–70°С for 2–5 h. On electrodes with low overvoltage of hydrogen evolution, the C=N double bonds in isonicotinoylisopropylidenehydrazine relatively readily undergo electrohydrogenation with atomic hydrogen.

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Authors and Affiliations

  1. Khoja Akhmet Yassawi International Kazakh–Turkish University, B. Sattarkhanov ave. 29, Turkestan, 161200, Kazakhstan

    S. A. Dzhumadullaeva, A. B. Baeshov, M. O. Altynbekova & B. S. Abzhalov

Authors
  1. S. A. Dzhumadullaeva
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  2. A. B. Baeshov
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  3. M. O. Altynbekova
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  4. B. S. Abzhalov
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Corresponding author

Correspondence to S. A. Dzhumadullaeva.

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Original Russian Text © S.A. Dzhumadullaeva, A.B. Baeshov, M.O. Altynbekova, B.S. Abzhalov, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 9, pp. 1373-1376.

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Dzhumadullaeva, S.A., Baeshov, A.B., Altynbekova, M.O. et al. Electrochemical synthesis of 1-isonicotinoyl-2-isopropylhydrazine on stationary solid electrodes. Russ J Appl Chem 88, 1559–1562 (2015). https://doi.org/10.1134/S1070427215090281

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  • DOI: https://doi.org/10.1134/S1070427215090281

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