Abstract
IR spectroscopy was used to study (5-nitrotetrazolato-N2)pentaaminecobalt(III) perchlorate (1) and {bis-[cis-(5-nitrotetrazolato-N2)]}tetraaminecobalt(III) perchlorate (2) and products of their decomposition under the action of laser light resonant in energy with d-d transitions observed in these complexes. The electronic spectra of complexes 1 and 2 are governed by d-d transitions of cobalt ions (1A1g → 1T2g at 328–330 nm and 1A1g → 1T1g at 455–466 nm) and ligand-metal charge transfer in a shorter wavelength range. Comparison of the vibration spectra of the decomposition products and starting complexes suggests that cobalt amminates decompose to give additional [−NO2] groups in unknown compounds.
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Original Russian Text © A.S. Tverjanovich, A.O. Aver’yanov, M.A. Ilyshin, Yu.S. Tverjanovich, A.V. Smirnova, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 2, pp. 221–226.
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Tverjanovich, A.S., Aver’yanov, A.O., Ilyshin, M.A. et al. Decomposition of cobalt(III) nitrotetrazolato amminates under the action of laser light. Russ J Appl Chem 88, 226–231 (2015). https://doi.org/10.1134/S1070427215020068
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DOI: https://doi.org/10.1134/S1070427215020068