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Influence of conversion on the initiating activity and molecular-weight characteristics of macroinitiators based on cobalt(II) 5-methyl-5-hexene-2,4-dionate

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Macroinitiators containing β-diketonate fragments were prepared by copolymerization of styrene with cobalt(II) 5-methyl-5-hexene-2,4-dionate. The influence of the degree of conversion at which the macroinitiators were isolated on their initiating activity in grafting of methyl methacrylate onto them and on the molecular-weight characteristics of the graft copolymers was examined.

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References

  1. Shevchenko, O.V., Burenkova, E.V., and Voloshanovskii, I.S., Vysokomol. Soedin., Ser. A, 2006, vol. 46, no. 8, pp. 1–6.

    Google Scholar 

  2. Shevchenko, O.V., Voloshanovskii, I.S., and Berbat, T.I., Zh. Prikl. Khim., 2006, vol. 79, no. 4, pp. 669–673.

    Google Scholar 

  3. Teyssie, Ph. and Smets, S., Makromol. Chem., 1958, vol. 26, no. 3, pp. 245-251.

  4. Voloshanovskii, I.S., Shevchenko, O.V., Berezhnitskaya, A.S., and Krasnova, E.A., Ukr. Khim. Zh., 2001, vol. 67, no. 5, pp. 5–10.

    CAS  Google Scholar 

  5. Rafikov, S.R., Pavlova, S.A., and Tverdokhlebova, I.I., Metody opredeleniya molekulyarnykh vesov i polidispersnosti vysokomolekulyarnykh soedinenii (Methods for Determination of Molecular Weights and Polydispersisitys of Macromolecular Compounds), Moscow: Akad. Nauk SSSR, 1963.

    Google Scholar 

  6. Voloshanovskii, I.S., Ukr. Khim. Zh., 2000, vol. 66, no. 2, pp. 44–48.

    Google Scholar 

  7. Nizel’skii, Yu.N., Kataliticheskie svoistva β-diketonatov metallov (Catalytic Properties of Metal β-Diketonates), Kiev: Naukova Dumka, 1983.

    Google Scholar 

  8. Voloshanovskii, I.S. and Shevchenko, O.V., Kompoz. Polim. Mater., 2000, vol. 22, no. 2, pp. 108–113.

    Google Scholar 

  9. Kopeikin, V.V., Panarin, E.F., Milevskaya, I.S., and Redi, N.S., Vysokomol. Soedin., Ser. A, 1977, vol. 19, no. 4, pp. 861–866.

    CAS  Google Scholar 

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Original Russian Text © O.V. Shevchenko, I.S. Voloshanovskii, E.V. Burenkova, 2010, published in Zhurnal Prikladnoi Khimii, 2010, Vol. 83, No. 2, pp. 303–307.

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Shevchenko, O.V., Voloshanovskii, I.S. & Burenkova, E.V. Influence of conversion on the initiating activity and molecular-weight characteristics of macroinitiators based on cobalt(II) 5-methyl-5-hexene-2,4-dionate. Russ J Appl Chem 83, 302–306 (2010). https://doi.org/10.1134/S1070427210020229

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  • DOI: https://doi.org/10.1134/S1070427210020229

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