Abstract
A new efficient procedure of synthesis of 3,4-dinitrotoluene from 3-nitro-4-aminotoluene was developed. Oxidation of 3,4-dinitrotoluene with an ozone-oxygen mixture to 3,4-dinitrobenzoic acid in the presence of cobalt(II) acetate was studied.
References
Lebedev, B.A., Dolmatov, V.Yu., Zubarev, P.S., et al., Khim.-Farm. Zh., 1988, no. 5, pp. 589–591.
US Patent 4 302 521.
Kunisaburo, T. and Kimie, Y., J. Chem. Soc. Jpn., 1964, vol. 85, no. 1, pp. 5–6.
Polish Patent 233 328.
US Patent 4 346 014.
Weygand-Hilgetag, Organisch-Chemische Experimentierkunst, Leipzig: Johann Ambrosius Barth, 1964.
Yakobi, V.A., Reaktsionnaya sposobnost’ organicheskikh soedinenii (Reactivity of Organic Compounds), Moscow: Mosk. Khim.-Tekhnol. Inst., 1978, issue 103, pp. 66–92.
Yakobi, V.A., Plakidin, V.L., Pokhila, S.E., et al., Zh. Obshch. Khim., 1963, vol. 33, pp. 3369–3373.
Galstyan, T.M., Galstyan, G.A., and Yakobi, V.A., in Trudy II Vsesoyuznoi konferentsii “Ozon, poluchenie i primenenie” (Proc. 2nd All-Union. Conf. “Ozone, Synthesis and Applications”), Moscow: Mosk. Gos. Univ., 1991. p. 73.
Nakamura, A. and Tsutsui, M., Principles and Applications of Homogeneous Catalysis, New York: Wiley, 1980.
Lur’e, Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook of Analytical Chemistry), Moscow: Khimiya, 1967.
Pluzhnik, I.M. and Galstyan, G.A., Neftekhimiya, 1999, vol. 39, no. 2, pp. 120–123.
Galstyan, A.G., Kudyukov, Yu.P., and Andreev, P.Yu., Kinet. Katal., 2003, vol. 43, no. 1, pp. 1–4.
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Original Russian Text © P.Yu. Andreev, E.V. Potapenko, I.P. Pogorelova, S.N. Krasil’nikov, A.N. Band, 2008, published in Zhurnal Prikladnoi Khimii, 2008, Vol. 81, No. 3, pp. 518–520.
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Andreev, P.Y., Potapenko, E.V., Pogorelova, I.P. et al. A new procedure for preparing 3,4-dinitrobenzoic acid. Russ J Appl Chem 81, 503–505 (2008). https://doi.org/10.1134/S1070427208030348
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DOI: https://doi.org/10.1134/S1070427208030348