Abstract
The dependence of the thermoelectric properties of the nanostructured bulk (Bi,Sb)2Te3 material on the composition and the spark plasma-sintering (SPS) temperature T SPS has been studied. It has been revealed that the Bi0.4Sb1.6Te3 solid solution sintered at a temperature of 450–500°C has a thermoelectric figure of merit ZT = 1.25–1.28. The dependence of thermoelectric properties on the sintering temperature T SPS above 400°C is correlated to the transformation of the fine structure of the material due to the rearrangement of point vacancy-donor defects in the process of repeated recrystallization. It has been established that point structural defects make a considerable contribution to the formation of the thermoelectric properties of nanostructured material.
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Original Russian Text © I.A. Drabkin, V.V. Karataev, V.B. Osvenskii, Yu.N. Parkhomenko, A.I. Sorokin, L.P. Bulat, G.I. Pivovarov, V.T. Bublik, N.Yu. Tabachkova, 2012, published in Izvestiya Vysshikh Uchebnykh Zavedenii. Materialy Elektronnoi Tekhniki, 2012, No. 3, pp. 18–21.
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Drabkin, I.A., Karataev, V.V., Osvenskii, V.B. et al. Thermoelectric properties of the (Bi,Sb)2Te3-based material obtained by spark plasma sintering. Russ Microelectron 42, 448–452 (2013). https://doi.org/10.1134/S1063739713080052
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DOI: https://doi.org/10.1134/S1063739713080052