Abstract
It has been inferred from experimental data that the hydrazine oxidation and decomposition reactions occur via a branched-chain and a nonbranched-chain mechanism, respectively. Taking into account the chain nature of these processes helps explain the observed regularities under the critical autoignition conditions, including their “anomalous” character and the combustion-to-explosion transition.
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Original Russian Text © V.V. Azatyan, A.A. Borisov, 2017, published in Kinetika i Kataliz, 2017, Vol. 58, No. 4, pp. 377–383.
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Azatyan, V.V., Borisov, A.A. Determining role of the chain mechanism of hydrazine oxidation and decomposition in kinetically controlled combustion and explosion. Kinet Catal 58, 355–361 (2017). https://doi.org/10.1134/S0023158417040012
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DOI: https://doi.org/10.1134/S0023158417040012