Skip to main content
SpringerLink
Log in

Kinetics and Mechanism of Thermal Decomposition of Guanidinium Nitrate and Its Mixtures with Ammonium Nitrate

  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

The kinetics of heat release in thermal decomposition of guanidinium and ammonium nitrates and their mixtures in the liquid phase in a calorimeter was studied. The kinetic equations of these processes and temperature dependences of the kinetic constants in these equations were evaluated. The oxidation rate constants of guanidinium and ammonium cations with molecular nitric acid in aqueous nitric acid solutions were found; these constants were calculated by solution of the reverse problem for salt melts. The temperatures and ΔH values of melting of the initial salts and their eutectic mixture were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Manelis, G.B., Nazin, G.M., Rubtsov, Yu.I., and Strunin, V.A., Termicheskoe razlozhenie i gorenie vzryvchatykh veshchestv i porokhov (Thermal Decomposition and Combustion of Explosives and Gun-powders), Moscow: Nauka, 1996.

    Google Scholar 

  2. Albert, A. and Serjeant, E., Ionization Constants of Acids and Bases. A Laboratory Manual, New York: Wiley, 1962.

    Google Scholar 

  3. Schoppelrei, J.W., Kieke, M.L., Wang, X., et al., J. Phys. Chem., 1996, vol. 100, no. 34, pp. 14343–14351.

    Google Scholar 

  4. Galyuk, O.S., Rubtsov, Yu.I., Malinovskaya, G.F., et al., Zh. Fiz. Khim., 1965, vol. 39, no. 9, pp. 2319–2322.

    Google Scholar 

  5. Rubtsov, Yu.I., Kazakov, A.I., Morozkin, S.Yu., et al., Zh. Prikl. Khim., 1984, vol. 57, no. 9, pp. 1926–1929.

    Google Scholar 

  6. Chedin, J., Feneant, S., and Vandoni, R., J. Chim. Phys., 1952, vol. 49, p. 109–125.

    Google Scholar 

  7. Kazakov, A.I., Andrienko, L.P., and Rubtsov, Yu.I., Izv. Akad. Nauk SSSR, Ser. Khim., 1980, no. 5, pp. 972–977.

    Google Scholar 

  8. Tekhnologiya ammiachnoi selitry (Production of Ammonium Nitrate), Olevskii, R.M., Ed., Moscow: Khimiya, 1978.

    Google Scholar 

  9. Termicheskie konstanty veshchestv (Thermal Constants of Substances), Glushko, V.P., Ed., Moscow: VINITI, 1968, issue 3.

    Google Scholar 

  10. Sprovochnik khimika (Chemist's Handbook), Nikol'skii, B.P., Ed., Moscow: Goskhimizdat, 1951, vol. 2.

    Google Scholar 

  11. Kurs fizicheskoi khimii (Course of Physical Chemistry), Gerasimov, Ya.I., Ed., Moscow: Khimiya, 1969, vol. 1.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    Yu. I. Rubtsov, A. I. Kazakov, D. B. Lempert & G. B. Manelis

Authors
  1. Yu. I. Rubtsov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. I. Kazakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. B. Lempert
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. B. Manelis
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rubtsov, Y.I., Kazakov, A.I., Lempert, D.B. et al. Kinetics and Mechanism of Thermal Decomposition of Guanidinium Nitrate and Its Mixtures with Ammonium Nitrate. Russian Journal of Applied Chemistry 77, 1083–1091 (2004). https://doi.org/10.1023/B:RJAC.0000044153.18228.b6

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:RJAC.0000044153.18228.b6

Keywords

Search

Navigation