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Synthesis, structures and magnetic properties of two 2D → 3D entangled Cobalt(II) coordination polymers

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Abstract

Two Co(II) coordination polymers, namely Co(HBTC)(4-bpdb)·H2O (1) and Co(HBTC)(3-bpdb)·H2O (2) (H3BTC = 1,3,5-benzenetricarboxylic acid, 4-bpdb = 1,4-bis-(4-pyridyl)-2,3-diaza-1,3-butadiene, 3-bpdb = 1,4-bis(3-pyridyl)-2,3-diaza-1,3- butadiene), have been hydrothermally synthesized and characterized both structurally and magnetically. Compound 1 exhibits a (2D → 3D) polythreaded architecture. It is assembled from HBTC2− ligands to form a 2D puckered (4,4) layer plus 4-bpdb ligands which are orientated above and below each layer. The structure of compound 2 consists of a 2D (3,5) wavelike sheet constructed from HBTC2− anions and 3-bpdb spacers. The uncoordinated carboxyl groups of the HBTC2− ligands protrude from both sides of the wavelike sheet to form a 2D → 3D interdigitated motif. The magnetic properties of both compounds are also investigated, indicating antiferromagnetic interactions between the adjacent metal centers.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 21271189, 51604307) and the Open-End Fund for the Valuable and Precision Instruments of Central South University.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Key Laboratory of Nonferrous Metal of Ministry of Education, Central South University, Changsha, 410083, China

    Qiao-Zhen Sun, Na-Wei Liu & Jun-Qiao Pan

  2. Key Laboratory of Catalysis and Materials Sciences of the State Ethnic Affairs Commission & Ministry of Education, College of Chemistry and Material Science, South-Central University for Nationalities, Wuhan, 430074, China

    Bing-Guang Zhang

  3. Chinese National Engineering Research Center for Control and Treatment of Heavy Metal Pollution (CNERC-CTHMP), School of Metallurgy and Environment, Central South University, Changsha, 410083, China

    Hui Liu

Authors
  1. Qiao-Zhen Sun
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  2. Na-Wei Liu
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  4. Bing-Guang Zhang
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  5. Hui Liu
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Correspondence to Bing-Guang Zhang.

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Sun, QZ., Liu, NW., Pan, JQ. et al. Synthesis, structures and magnetic properties of two 2D → 3D entangled Cobalt(II) coordination polymers. Transit Met Chem 42, 517–524 (2017). https://doi.org/10.1007/s11243-017-0156-6

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  • DOI: https://doi.org/10.1007/s11243-017-0156-6

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