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Disproportionation reaction of iodous acid, HOIO. Determination of the concentrations of the relevant ionic species H+, H2OI+, and IO3 −

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Abstract

The pseudo-equilibrium concentrations of the H+, IO3 −, and H2OI+ ions, kinetically very important species in the disproportionation reaction of iodous acid, have been determined from the equilibrium dissociation reactions of sulfuric and iodous acids in the quasi-stationary state. The values observed were higher than the concentration of the protonated ion of hypoiodous acid.

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References

  1. R.M. Noyes, S.D. Furrow, J. Am. Chem. Soc. 45, 104 (1982)

    Google Scholar 

  2. Z. Noszticzius, E. Noszticzius, Z.A. Schelly, J. Phys. Chem. 87, 510 (1983)

    Article  CAS  Google Scholar 

  3. R.M. Noyes, L.V. Kalachev, R.J. Field, Phys. Chem. 99, 3514 (1995)

    Article  CAS  Google Scholar 

  4. S.D. Furrow, J. Phys. Chem. 91, 2129 (1987)

    Article  CAS  Google Scholar 

  5. I. Lengyel, J. Li, K. Kustin, I.R. Epstein, J. Amer. Chem. Soc. 118, 3708 (1996)

    Article  CAS  Google Scholar 

  6. S. Marković, N. Rakićević, Đ. Mišljenović, J. Serb. Chem. Soc. 67, 347 (2002)

    Article  Google Scholar 

  7. S. Marković, B. Petrovic, Int. J. Chem. Kinet. 89, 3 (2010)

    Google Scholar 

  8. I. Valent, L. Adamičkova, P. Ševčik, J. Phys. Chem. 102, 7576 (1998)

    Article  CAS  Google Scholar 

  9. K. Kissimonova, I. Valent, L. Adamičkova, P. Ševčik, Chem. Phys. Lett. 341, 345 (2001)

    Article  CAS  Google Scholar 

  10. S. Kéki, G. Sźkely, M.T. Beck, J. Phys. Chem. A 107, 73 (2003)

    Article  Google Scholar 

  11. C.D. O’ Dowd, J.L. Jimenez, R. Bahreini, C.R. Flagon, H.J. Sienfeld, K. Hämeri, L. Pirjola, M. Kulmala, S.G. Jennings, T. Hoffman, Nature 417, 632 (2002)

    Article  Google Scholar 

  12. J.L. Jimenez, D.R. Cocker, R. Bahreini, H. Zhuang, R. Flagan, J.H. Steinfeld, T. Hoffman, C. O’ Dowd, J. Geophys. Res. 108, D10 (2003)

    Google Scholar 

  13. J.M. Mäkaelä, T. Hoffman, C. Holzke, M. Väkaevä, T. Suni, T. Mattila, P.P. Aalto, U. Tapper, E. Kaupinen, C. O’Dowd, J. Geophys. Res. 107, D19 (2002)

    Google Scholar 

  14. N. Begović, Z. Marković, S. Anić, Lj Kolar-Anić, J. Phys. Chem. 108, 651 (2004)

    Article  Google Scholar 

  15. D. Dyrsen, D. Jagner, F. Wengelin, Computer calculation of ionic equilibria and titration procedures (Almqvist & Wiksell, Stockholm, 1968)

    Google Scholar 

  16. A.G. Amelin, Tekhnologya Sernoi Kisloty (Khimia, Moskva, 1983)

    Google Scholar 

  17. A. Misra, P. Marshall, J. Phys. Chem. 102, 9056 (1998)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge financial support from the Ministry of Education, Science and Technological development, Republic of Serbia (project no. 172011).

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Authors and Affiliations

  1. Faculty of Technological Sciences, University of Priština, Kneza Miloša 7, 38220, Kosovska Mitrovica, Serbia

    Smiljana Marković

  2. Military Academy, Generala Pavla Jurisica Sturma 33, 11000, Belgrade, Serbia

    Radovan Karkalic

  3. Faculty of Science, University of Kragujevac, R. Domanovica 12, 34000, Kragujevac, Serbia

    Biljana Petrović

Authors
  1. Smiljana Marković
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  2. Radovan Karkalic
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  3. Biljana Petrović
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Correspondence to Biljana Petrović.

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Marković, S., Karkalic, R. & Petrović, B. Disproportionation reaction of iodous acid, HOIO. Determination of the concentrations of the relevant ionic species H+, H2OI+, and IO3 − . Res Chem Intermed 41, 1293–1300 (2015). https://doi.org/10.1007/s11164-013-1273-2

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  • DOI: https://doi.org/10.1007/s11164-013-1273-2

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