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Cyclodextrin-modified MCM-41 for selective double bond migration

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Abstract

Cyclodextrin-modified MCM-41 with relatively high surface area above 1,100 m2/g has been prepared via simple hybridization of cetyltrimethylammonium bromide and cyclodextrin. The modified MCM-41 showed fairly good catalytic performance (high activity and selectivity) in the double bond migration of 2-butene into 1-butene.

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Acknowledgment

This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (grant number: 2009-0065498).

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Authors and Affiliations

  1. Department of Chemical Engineering, Kongju National University, Cheonan, 330-717, Korea

    Jong-Ki Jeon

  2. School of Environmental Engineering, University of Seoul, Seoul, 130-743, Korea

    Young-Kwon Park

  3. Division of Advanced Materials Engineering, Kongju National University, Cheonan, 330-717, Korea

    Jin-Heong Yim

Authors
  1. Jong-Ki Jeon
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  2. Young-Kwon Park
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Correspondence to Jin-Heong Yim.

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Jeon, JK., Park, YK. & Yim, JH. Cyclodextrin-modified MCM-41 for selective double bond migration. Res Chem Intermed 36, 661–667 (2010). https://doi.org/10.1007/s11164-010-0202-x

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  • DOI: https://doi.org/10.1007/s11164-010-0202-x

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