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Effect of the nano-fibrillation of bamboo pulp on the thermal, structural, mechanical and physical properties of nanocomposites based on starch/poly(vinyl alcohol) blend

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Abstract

The current work aimed to evaluate the influence of adding bamboo cellulose nanofibrils on the performance of poly(vinyl alcohol)—PVA and modified cassava starch—FMM blend nanocomposites. Nanofibrils were produced after 5 and 30 passes through the mechanical defibrillator. Blends formed from PVA and FMM in an 80/20 ratio were used for casting preparation of the nanocomposites reinforced with 6.5% of nanofibrils. Atomic force microscopy showed the deconstruction of the fiber wall with release of the cellulose nanofibrils. A higher degree of nano-fibrillation occurred after 30 passes. The interaction between the polymers and the reinforcement after 30 passes was verified by Fourier transform infrared spectroscopy and scanning electronic microscopy. The higher nano-fibrillation promoted higher homogeneity, cohesion and more compact structure, thus promoting the formation of larger well-defined crystals, which acted as nucleating agents in the matrix, as demonstrated by differential scanning calorimetry and X-ray diffractrometry. It led to improvements of the physical, thermal and mechanical properties of the nanocomposites, conferring them great potential for applications in the plastic film industries.

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Acknowledgments

The authors thank the Fundação de Amparo à Pesquisa do Estado de Minas Gerais (FAPEMIG), Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) and Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES). Thanks, are also given to the Centro Federal de Educação Tecnológica de Minas Gerais (CEFET-MG), Rede Temática de Engenharia de Materiais (REDEMAT). Thanks also to the Instituto de Tecnologia de Alimentos/Centro de Tecnologia de Embalagem (ITAL/CETEA), DCF (UFLA-MG) and Forestry nanotechnology laboratory (UFLA-MG).

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Authors and Affiliations

  1. Departamento de Eletromecânica, CEFET-MG, Centro Federal de Educação Tecnológica de Minas Gerais, Campus Araxá, Av. Ministro Olavo Drummond, 25, Bairro São Geraldo, Araxá, MG, CEP 38180-510, Brazil

    Mario Guimarães Junior

  2. Instituto de Tecnologia de Alimentos, Centro de Tecnologia de Embalagem (ITAL/CETEA), Avenida Brazil, 2880, Campinas, SP, CEP 13070-178, Brazil

    Fábio Gomes Teixeira

  3. Departamento de Ciências Florestais, UFLA-MG, Universidade Federal de Lavras, Cx P. 3037, Lavras, MG, CEP 37200-000, Brazil

    Gustavo Henrique Denzin Tonoli

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  1. Mario Guimarães Junior
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  3. Gustavo Henrique Denzin Tonoli
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Correspondence to Mario Guimarães Junior.

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Guimarães Junior, M., Teixeira, F.G. & Tonoli, G.H.D. Effect of the nano-fibrillation of bamboo pulp on the thermal, structural, mechanical and physical properties of nanocomposites based on starch/poly(vinyl alcohol) blend. Cellulose 25, 1823–1849 (2018). https://doi.org/10.1007/s10570-018-1691-9

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