Issue 93, 2023
From the journal:

Chemical Communications

Water vapour induced structural flexibility in a square lattice coordination network†

Kyriaki Koupepidou, ORCID logo a   Andrey A. Bezrukov, ORCID logo a   Dominic C. Castell, ORCID logo a   Debobroto Sensharma, ORCID logo a   Soumya Mukherjee ORCID logo a  and  Michael J. Zaworotko ORCID logo *a  

* Corresponding authors

a Bernal Institute, Department of Chemical Sciences, University of Limerick, Limerick V94 T9PX, Republic of Ireland
E-mail: xtal@ul.ie

Abstract

Herein, we introduce a new square lattice topology coordination network, sql-(1,3-bib)(ndc)-Ni, with three types of connection and detail its gas and vapour induced phase transformations. Exposure to humidity resulted in an S-shaped isotherm profile, suggesting potential utility of such materials as desiccants.

Graphical abstract: Water vapour induced structural flexibility in a square lattice coordination network

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Article information

DOI
https://doi.org/10.1039/D3CC04109C
Article type
Communication
Submitted
01 Sep 2023
Accepted
26 Oct 2023
First published
30 Oct 2023
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2023,59, 13867-13870

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Water vapour induced structural flexibility in a square lattice coordination network

K. Koupepidou, A. A. Bezrukov, D. C. Castell, D. Sensharma, S. Mukherjee and M. J. Zaworotko, Chem. Commun., 2023, 59, 13867 DOI: 10.1039/D3CC04109C

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