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Journal of Aerosol Science
Volume 32, Issue 5, May 2001, Pages 583-599
 
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doi:10.1016/S0021-8502(00)00104-X    How to Cite or Link Using DOI (Opens New Window)
Copyright © 2001 Elsevier Science B.V. All rights reserved.

Space-charge effects in nanoparticle processing using the differential mobility analyzer

Renato P. Camata1, Corresponding Author Contact Information, E-mail The Corresponding Author, , a, Harry A. Atwatera and Richard C. Flaganb

a Thomas J. Watson Laboratory of Applied Physics, California Institute of Technology, Pasadena, CA 91125, USA b Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA

Received 9 November 1999;
revised 21 August 2000;
accepted 28 August 2000
Available online 14 March 2001.

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Abstract

We report the observation of mobility classification breakdown due to strong space-charge effects during nanoparticle processing in a radial differential mobility analyzer (DMA). A simple dimensionless group, the space-charge number, is introduced to help identify the conditions for which this phenomenon becomes important. Our analysis suggests a few DMA design features and operation conditions that should enable the accurate classification of ultrafine aerosols with high concentrations of charged particles.

Author Keywords: Differential mobility analyzer; Charged particles; Space charge; Ultrafine aerosols

Article Outline

1. Introduction
2. High-throughput size classification and materials synthesis
3. Attempting mobility classification on highly charged aerosols
3.1. Aerosol generation and charging in the sub-10-nm size range
3.2. Maximum number concentration of charged particles in the DMA
4. Estimating the intensity of the space-charge effect
5. Toward a DMA for high-throughput nanoparticle processing
6. Summary
Acknowledgements
References








 
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