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The Diels–Alder Reaction in Phosphonium Ionic Liquid Catalysed by Metal Chlorides, Triflates and Triflimides

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Abstract

Phosphonium ionic liquid (IL)—trihexyl-tetradecylphosphonium bis(trifluoromethylsulfonyl)imide, has been tested as the medium in the Diels–Alder reaction between cyclopentadiene and dienophiles from the group of α,β-unsaturated esters, aldehydes and ketones. Catalytic activities of a few metal chlorides, triflates and bis-triflimides in this reaction have been compared. The recycling of the catalyst with phosphonium IL was studied.

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Acknowledgments

The research was supported by Polish grant No. N205 055 31/2491.

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  1. Department of Organic Chemical Technology, Szczecin University of Technology, Pułaski Str. 10, 70-322, Szczecin, Poland

    Ewa Janus & Waldemar Stefaniak

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  1. Ewa Janus
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  2. Waldemar Stefaniak
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Correspondence to Ewa Janus.

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Janus, E., Stefaniak, W. The Diels–Alder Reaction in Phosphonium Ionic Liquid Catalysed by Metal Chlorides, Triflates and Triflimides. Catal Lett 124, 105–110 (2008). https://doi.org/10.1007/s10562-008-9431-7

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  • DOI: https://doi.org/10.1007/s10562-008-9431-7

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