Issue 33, 2018

Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands

Abstract

Dinitrogen-bridged dititanium and dizirconium complexes bearing anionic pyrrole-based PNP-type pincer ligands are prepared and characterized by X-ray analysis. Their catalytic activity is investigated toward reduction of nitrogen gas into ammonia and hydrazine under mild reaction conditions.

Graphical abstract: Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands

Supplementary files

Article information

Article type
Communication
Submitted
05 Jul 2018
Accepted
24 Jul 2018
First published
25 Jul 2018

Dalton Trans., 2018,47, 11322-11326

Author version available

Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands

Y. Sekiguchi, F. Meng, H. Tanaka, A. Eizawa, K. Arashiba, K. Nakajima, K. Yoshizawa and Y. Nishibayashi, Dalton Trans., 2018, 47, 11322 DOI: 10.1039/C8DT02739K

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