The Journal of Antibiotics
Online ISSN : 1881-1469
Print ISSN : 0021-8820
ISSN-L : 0021-8820
SYNTHESIS OF 5-epi-TREHAZOLIN (TREHALOSTATIN)
YOSHIYUKI KOBAYASHIHIDEKI MIYAZAKIMASAO SHIOZAKIHIDEYUKI HARUYAMA
Author information
JOURNAL FREE ACCESS

1994 Volume 47 Issue 8 Pages 932-938

Details
Abstract

Synthesis of 5-epi-trehazolin (trehalostatin) (2) was accomplished via the crucial intermediate, epoxide (), from D-glucose. The stereochemistry of epoxide () and its isomer () which were obtained from Sharpless epoxidation, was determined by comparison between the NMR relaxation times of relevant protons.

Content from these authors
© Japan Antibiotics Research Association
Previous article Next article
feedback
Top