The development of technological and vocational education has been changing from the traditional economic development to the concept of environmental sustainable development. Technological and vocational education has to recognize that though the increasing consciousness of social environmental protection will influence the cost of management and the volition of investment of enterprises, it also improves our living quality and that the social benefit is no fewer than the economic sacrifice caused by sluggish growth. The artic1e tries to discuss the role and function of environmental education in technological and vocational education from the meaning of environmental problems, the purpose and content of environmental education. The article also, in accordance with the characteristics of vocational environmental education, presents types, concepts and connections of the education. Furthermore, an integrated instructional model is presented in order to accomplish the objective of vocational environmental education and to cultivate technological talents with international viewpoints.