The purpose of this study is to explore the relation among travel motivation, destination attraction, perceived value, overall satisfaction and post-travel behavioral intentions. The data collected from the tourist who visited Taichung-Stock 20 and Art Site of Chiayi Railway Warehouse. The process tool was SPSS for Windows 10.0, descriptive statistical method, factor analysis, T-test, correlation analysis and cluster analysis were used for data analysis. In addition, LISREL is applied to investigate the relationship among the five latent variables. The results of the study indicate that destination attraction have a direct significant impact on the perceived value, perceived value have the direct significant impact on the overall satisfaction and post-travel behavioral intentions, and overall satisfaction have a direct significant impact on the post-travel behavioral intentions. It indicates higher overall satisfaction will increase the recommend intention and re-travel intention of tourist.