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環境香煙微粒的粒徑成份分佈

The Size-Composition Distribution of Environmental Tobacco Smoke

摘要


本研究的主要目的在於探討有人吸煙的室內環境中懸浮微粒的粒徑與成份分布。因粒徑是決定微粒在呼吸道內不同位置沉積的主要因素,透過環境香煙微粒杜徑成份分布的研究,可進一步了解環境香煙對人體健康危害的機轉。 本研究選擇三個撞球場為採樣地點,以微孔均勻沉積衛擊器(MOUDI(上标 TM))進行空氣中懸浮微粒採樣。此種衛擊器原有八階,本研究只使用其中四階。其裁取粒徑分別為0.17、0.56、1.8、10μm。採樣流量為30L/min。採樣時間依氣懸微粒濃度而定,介於3~5小時。香煙中的solanesol性質安定,且佔有一定的質量比例,故選用為香煙從紅成份的追蹤劑。Solanesol在高溫時易分解,所以樣本經萃取後再作衍生處理,然後使用氣相層析儀連接火燄離子檢測器分析solanesol衍生物。 根據現場採樣結果,三家撞球場細微粒(氣動直裡小於2.5μm)濃度介於53~461μg/立方公尺之間,平均189μg/立方公尺;solanesol濃度介於0.259~9.91μg/立方公尺之間,平均3.03μg/立方公尺;solanesol佔細微粒質量分率介於0.0037~0.0244之間,平均0.0150。分布在大於0.56μm微紅中的solanesol佔所有微粒中solanesol的百分比介於10%~32%之間。根據文獻,推估細微粒由香煙貢獻的百分比平均介於700%~93%。

並列摘要


The primary objective of this study is to investigate the size-composition distribution of environmental tobacco smoke (ETS) in indoor environment. Particle size is one of the major factors which influence the rates and sites of particle deposition in the human respiratory tract. Study of the size-composition distribution of the environmental tobacco smoke would therefore lead to a better understanding of its health effects. Samples of airborne particles were obtained from three billiard parlors in Taipei by a micro-orifice uniform deposit impactor (MOUDI(superscript TM)). While the original MOUDI(superscript TM) has eight stages, only four stages and the after- filter were used in this study. The cut sizes of the four stages are 0.17, 0.56, 1.8, 10μm respectively. The sampling flowrate was 30L/min and the duration of sampling was in the range of 3~5 hrs, depending on the indoor particulate concentration. Solanesol was chosen as a tracer in this study, because it is stable and has a relatively fixed mass ratio in tobacco smoke particles. The solanesol extracted from the samples was derivatized and then analyzed by the GC-FID method. The derivatization was made to avoid the decomposition of solanesol at higher temperatures. The results show that the mass concentration of fine particles (smaller than 2.5μm in aerodynamic diameter) is in the range of 53~461μg/m^3, with an average of 189μg/m^3; the solanesol concentration is in the range of 0.259~9.91μg/m^3, with an average of 3.03μg/m^3 the mass fraction of solanesol in fine particles is in the range of 0.0037~0.0244, with an average of 0.0150; and 10~32% (average 22%) of ETS are in particles larger than 0.56μm in aerodynamic diameter. The estimated contribution of ETS to fine particles is in the range of 70~93%.

被引用紀錄


林漢翔(2013)。台南地區大學生撞球專項課程參與動機與滿意度之研究〔碩士論文,長榮大學〕。華藝線上圖書館。https://doi.org/10.6833/CJCU.2013.00018

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