双面进光太阳能电池透明对电极研究进展

doi:10.6023/A18050197

化学学报 ›› 2018, Vol. 76 ›› Issue (9): 681-690.DOI: 10.6023/A18050197 上一篇下一篇

综述

双面进光太阳能电池透明对电极研究进展

杨英^a,b,c, 陈甜^a,b,c, 潘德群^a,b,c, 张政^a,b,c, 郭学益^a,b,c

a 中南大学冶金与环境学院长沙 410083;
b 有色金属资源循环利用湖南省重点实验室长沙 410083;
c 有色金属资源循环利用湖南省工程研究中心长沙 410083

投稿日期:2018-05-12 发布日期:2018-06-29
通讯作者: 郭学益 E-mail:xyguo@csu.edu.cn
作者简介:杨英,副教授,武汉大学博士毕业.长期从事材料物理化学及新能源材料与器件的科研工作,对固态高分子电解质以及固态染料敏化太阳能电池、量子点太阳能电池及钙钛矿太阳能电池有夯实的理论和实践基础.于2013~2014年间在美国怀俄明大学完成博士后研究工作.现工作于中南大学冶金与环境学院.主要研究方向:新能源材料与器件;郭学益,教授,1995于中南大学获得博士学位.1997年完成博士后研究工作,1999~2000年在日本佐贺大学理工学部机能物质化学科担任研究员,2000~2003年在日本东京大学国际产学共同研究中心担任客员教授.现工作于中南大学冶金与环境学院.主要研究方向:资源循环利用及环境材料.
基金资助:
项目受国家自然科学基金（No.61774169）、中南大学创新驱动计划项目（No.2016CX022）、留学回国基金资助以及湖南省自然科学基金（No.2016JJ3140）、中南大学研究生创新项目（Nos.1053320170116，1053320170565）和中南大学本科生创新项目（Nos.cx20170271，201710533300）资助.

Research Progress of Bifacial Solar Cells with Transparent Counter Electrode

Yang Ying^a,b,c, Chen Tian^a,b,c, Pan Dequn^a,b,c, Zhang Zheng^a,b,c, Guo Xueyi^a,b,c

a Central South University, School of Metallurgy and Environment, Changsha 410083;
b Hunan Key Laboratory of Nonferrous Metal Resources Recycling, Changsha 410083;
c Hunan Engineering Research Center of Nonferrous Metal Resources Recycling, Changsha 410083

Received:2018-05-12 Published:2018-06-29
Contact: 10.6023/A18050197 E-mail:xyguo@csu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (No. 61774169), Third Innovation Driven Project of Central South University (No. 2016CX022), Scientific Research Foundation for the Returned overseas Chinese Scholar, Natural Science Foundation of Hunan Province (No. 2016JJ3140), Graduate student of Central South University (Nos. 1053320170116, 1053320170565) and Undergraduate student of Central South University (Nos. cx20170271, 201710533300).

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摘要/Abstract

近年来，太阳能电池（包括染料敏化、量子点敏化及钙钛矿太阳能电池）因其成本低、质量轻、效率高受到研究人员的广泛关注.双面进光太阳能电池是太阳光能通过光阳极以及透明对电极同时入射的器件，是近年来扩宽太阳能电池光利用率及能效以达到提高器件光电性能的主要手段，其中透明对电极的性能直接影响器件的背面进光效率，因此研究对电极对提高双面进光太阳能电池光电转化效率十分必要.本文针对传统对电极透光性低，成本高，光利用率低等问题，与双面进光的高光电转换效率以及低成本等特点对比，综合分析了透明对电极材料的选择及界面修饰改性等对双面进光染料敏化、量子点敏化及钙钛矿太阳能电池光电性能的影响及其应用前景.

关键词: 透明对电极, 双面进光太阳能电池, 染料敏化太阳能电池, 量子点太阳能电池, 钙钛矿太阳能电池

In recent years, solar cells (including dye-sensitized solar cells (DSSCs), quantum dots sensitized solar cells (QDSCs), and perovskite solar cells (PSCs)) have attracted wide attention due to their low cost, light weight, and high efficiency. Compared with traditional solar cells with opaque counter electrodes where the sunlight can only pass from the photoanode, bifacial solar cells, which are composed of photoanode, electrolyte, transparent counter electrode, hole transport layer can realize the purpose that sunlight can pass through the photoanode and the transparent counter electrode (CE) at the same time, which can reduce the loss of sunlight and greatly broad the light utilization of device to achieve improved opto-electronic performance. In the entire electrochemical cycle, the transparent counter electrode is regarded as reducing agent in reducing the oxidation state I₃^- in the electrolyte to the reduced state I^- so the electrocatalytic activity, chemical stability, electrical conductivity of the transparent counter electrode directly influences the rear side photo-to-electricity efficiency of device and the preparation of transparent counter electrodes is significantly important for the device. Therefore, it is necessary to study the effect of the counter electrode on the photoelectric conversion efficiency of the bifacial solar cells. In view of the problems of low transmittance, high cost, and low light utilization of traditional CE, the transparent CE of bifacial solar cells with high power conversion efficiency and low cost are preferred. The transparent CE of bifacial DSSCs, QDSCs and PSCs are comprehensively discussed in this paper. The influence of materials choosing and interfacial modification methods of transparent counter electrode on the photovoltaic performances of bifacial devices are analyzed. The transparent counter electrodes materials mainly include metals and alloys, sulfides, selenides, conductive polymers, and so on. In conclusion, bifacial solar cells mainly have the following problems:high reflectivity of metal electrodes, corrosion of the sulfide on the electrodes and the stability of the conductive polymers. The further application prospects of these kinds of bifacial solar cells is proposed.

Key words: transparent electrode, bifacial solar cells, dye-sensitized solar cells, quantum dots sensitized solar cells, perovskite solar cells

引用此文

杨英, 陈甜, 潘德群, 张政, 郭学益. 双面进光太阳能电池透明对电极研究进展[J]. 化学学报, 2018, 76(9): 681-690.

Yang Ying, Chen Tian, Pan Dequn, Zhang Zheng, Guo Xueyi. Research Progress of Bifacial Solar Cells with Transparent Counter Electrode[J]. Acta Chim. Sinica, 2018, 76(9): 681-690.

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双面进光太阳能电池透明对电极研究进展

Research Progress of Bifacial Solar Cells with Transparent Counter Electrode

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