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2017, vol. 58, br. 4, str. 487-497
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Efikasnost zeolita i apatita na mobilnost teških metala u zemljištima praćena preko test kulture Sinapis Alba
Efficiency of zeolite and apatite on the mobility of heavy metals in the soil through the Sinapis Alba as test culture
aInstitut za tehnologiju nuklearnih i drugih mineralnih sirovina - ITNMS, Beograd, Srbija bUniverzitet u Beogradu, Poljoprivredni fakultet, Srbija cUniverzitet u Kragujevcu, Agronomski fakultet, Čačak, Srbija
e-adresa: m.grubisic@itnms.ac.rs
Projekat: Razvoj tehnologija i proizvoda na bazi mineralnih sirovina i otpadne biomase u cilju zaštite resursa za proizvodnju bezbedne hrane (MPNTR - 31003) Osvajanje tehnoloških postupaka dobijanja ekoloških materijala na bazi nemetaličnih mineralnih sirovina (MPNTR - 34013)
Sažetak
Zaštita i unapređenje životne sredine, posebno očuvanje i zaštita zemljišta, postao je danas jedan od najznačajnijih problema savremenog sveta. Istraživanja u ovom radu imaju za cilj ispitivanje efikasnosti dva tipa mineralnih sirovina, zeolita i apatita na imobilzaciju teških metala i sprečavanja njihovog uključenja u lanac ishrane. Ispitivani su Pb, Cd, Zn i radionuklid (U), u dozama 10 mg kg-1 Cd, 500 mg kg-1 Pb, 300 mg kg-1 Zn i 300 mg kg-1 U na zemljištima različitih fizičko-hemijskih karakteristika (peskoviti černozem i pseudoglej). Efikasnost mineralnih sirovina kroz procese adsorpcije/precipitacije polutanata u zemljištima ispitivana je preko vegetacionih ogleda sa test kulturom-biljke slačice, Sinapis Alba, preko sadržaja Pb, Cd, Zn i U u korenu i nadzemnoj masi. Rezultati ukazuju da su i zeolit i apatit, domaćeg porekla, u dozi 20 g kg-1 zemljišta, doprineli imobilizaciji ispitivanih polutanata, da njihova efikasnost zavisi od fizičko hemijskih osobina polutanta i kiselosti zemljišta, tako da njihovo korišćenje opravdava primenu u tehnologijama remedijacije kontaminiranih zemljišta a u funkciji održivosti poljoprivredne proizvodnje i proizvodnji zdravstveno bezbedne hrane.
Abstract
Protection and improvement of the environment, especially preservation and protection of the land, has become one of the most important problems of the modern world today. The research in this paper aims at examining the efficiency of two types of mineral raw materials, zeolites and apatites on the immobilization of heavy metals and preventing their inclusion in the food chain. Pb, Cd, Zn and radionuclides (U) were tested. In doses 10 mg kg-1Cd, 500 mg kg-1 Pb, 300 mg kg-1Zn i 300 mg kg-1U. On soil with various physico-chemical properties (sandy chernozem and pseudocley). The efficiency of mineral resources through the adsorption / precipitation of pollutants in the soil was investigated through vegetation experiments with the test culture-plant, Sinapis Alba, through the contents of Pb, Cd, Zn and U in the root and overgrowth mass. The results indicate that both, zeolite and apatite in dosage 20 g kg-1 soils, have contributed to the immobilization of the investigated pollutants, that their effectiveness depends of soils type and their acidity, kinds of pollutant, so their use is justified in the application of technologies for the remediation of contaminated soils in the function of sustainability of agricultural production and the production of healthy food.
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Reference
|
|
*** (2010) Uredba o programu sistemskog praćenja kvaliteta zemljišta, indikatorima za ocenu rizika od degradacije zemljišta i metodologiji za izradu remedijacionih programa. Sl. glasnik RS, br. 88
|
|
*** (1966) Hemijske metode ispitivanja zemljišta. u: Priručnik za ispitivanje zemljišta, Beograd-Zemun, knjiga 1, 1-279
|
|
*** (1999) Technologically enhanced naturally occurring radioactive material. NRC, TENORM, https://www.nrc.gov/docs/ML0106/ML010670073.pdf, 18.06.2017
|
|
Blum, W.E. (2002) Environmental protection through sustainable soil management: A holistic approach. u: Pagliai M., Jones R. [ur.] Sustainable land management: Environmental protection: A soil physical approach, Advan. Geoecol. 35, 1-8
|
|
Boisson, J., Ruttens, A., Mencha, M., Vangronsveld, J. (1999) Evaluation of hydroxyapatite as a metal immobilizing soil additive for the remediation of polluted soils. Part 1. Infuence of hydroxyapatite on metal exchangeability in soil, plant growth and plant metal accumulation. Environmental Pollution, 225-233; 104
|
1
|
Chlopecka, A., Adriano, D.C. (1997) Influence of zeolite, apatite and Fe-oxide on Cd and Pb uptake by crops. Science of the total environment, 207(2-3): 195-206
|
1
|
Conca, J.L. (1997) Phosphate-induced metal stabilization (PIMS): Final report to the U.S. Environmental Protection Agency. Triangle Park, NC, 68D60023, Res
|
|
Entry, J.A., Watrud, L.S., Reeves, M. (1999) Accumulation of 137Cs and 90Sr From Contaminated Soil by Three Grass Species Inoculated With Mycorrhizal Fungi. Environmental Pollution, 449-457; 104
|
|
Entry, J.A., Watrud, L.S., Manasse, R.S., Vance, N.C. (1997) Phytoremediation and reclamation of soils contaminated with radionuclides. u: Kruger E.L., Anderson T.A.Coats J.R. [ur.] Phytoremediation of soil and water contaminants, New York: American Chemical Society, Chapter 22, 299-306
|
|
Glass, D.J. (2000) Economic potential of phytoremediation. u: Ensley B., Raskin I. [ur.] Phytoremediation of Toxic Metals: Using Plants to Clean-Up the Environment, John Wiley & Sons, p. 15-31
|
|
Grubišić, M., Boškovič-Rakočević, Lj., Stojanović, M., Mihajlović, M., Milojković, J., Hojka, Z. (2011) Polupropustljive barijere na bazi zeolita i apatita za sprečavanje kontaminacije zemljišta i podzemnih voda. u: III Savetovanje Stanje i perspektive deponija pepela, šljake i jalovine u termoelektranama i rudnicima, 226-235
|
|
Grubišić, M., Stojanović, M., Adamović, M. (2006) Station and Important Plants in Decontamination of soils and waste water-Phytoremediation. u: Radionuclide contamination of Serbian soil and remediation possibility, Beograd, p. 291-317
|
1
|
Hseu, Z. (2004) Evaluating heavy metal contents in nine composts using four digestion methods. Bioresource technology, 95(1): 53-9
|
|
Khan, E., Muhammad, A.S. (2013) Phytoremediation of heavy metals-Concepts and applications. Chemosphere, 91 (7): 869-881
|
|
Laperche, V., Logan, T.J., Gaddam, P., Traina, S.J. (1997) Effect of apatite amendments on plant uptake of lead from contaminated soil. Environmental Science and Technology, 31(10): 2745-2753
|
3
|
Ma, Q.Y., Traina, S.J., Logan, T.J. (1993) In situ lead immobilization by apatite. Environmental Science and Technology, 27(9): 1803
|
|
Mahabadi, A.A., Hajabbasi, M.A., Khademi, H., Kazemian, H. (2007) Soil cadmium stabilization using an Iranian natural zeolite. Geoderma, 137(3-4), 388-393
|
|
Ostroski, I.C., Barros, M.A.S.D., Silva, E.A., Dantas, J.H., Arroyo, P.A., Lima, O.C.M. (2009) A comparative study for the ion exchange of Fe(III) and Zn(II) on zeolite NaY. Journal of hazardous materials, 161(2-3): 1404-12
|
|
Prasad, M.N.V., Freitas, H.M.O. (2003) Metal hyperaccumulation in plants-Biodiversity prospecting for phytoremediation technology. Electronic Journal of Biotechnology, 6(3): 225-321
|
|
Puschenreiter, M., Horak, O., Friesl, W. (2005) Hartl3Low-cost agricultural measures to reduce heavy metal transfer into the food chain - a review. Plant soil environ, 51 (1): 1-11
|
2
|
Raičević, S., Kaluđerović-Radoičić, T., Zouboulis, A.I. (2005) In situ stabilization of toxic metals in polluted soils using phosphates: theoretical prediction and experimental verification. Journal of hazardous materials, vol. 117, br. 1, str. 41-53
|
|
Shi, G., Chen, Z., Xu, S., Zhang, J., Wang, L., Bi, C., Teng, J. (2008) Potentially toxic metal contamination of urban soils and roadside dust in Shanghai, China. Environmental Pollution, 251-260; 156
|
|
Shi, W., Shao, L., Shao, M., Du, S. (2009) Progress in the remediation of hazardous heavy metalpolluted soils by natural zeolite. J Hazard Mater, 170 (1), 1-6
|
|
Shi, W., Shaoa, H., Li, H., Shaoa, M., Dua, S. (2009) Progress in the remediation of hazardous heavy metal-polluted soils by natural zeolite. J. Hazar. Materials, 1-6; 170
|
4
|
Sprynskyy, M., Buszewski, B., Terzyk, A.P., Namiesnik, J. (2006) Study of the selection mechanism of heavy metal (Pb2+, Cu2+, Ni2+, and Cd2+) adsorption on clinoptilolite. Journal of Colloid and Interface Science, 304(1): 21
|
|
Stojanović, M., Grubišić, M., Stevanović, D., Milojković, J., Ileš, D. (2008) Remediation of the Serbian soils contaminated by radionuclides in the function of the sustainable development. Chemical Industry and Chemical Engineering Quarterly / CICEQ, vol. 14, br. 4, str. 265-267
|
|
Stojanović, M., Milojković, J. (2011) Phytoremediation of uranium contaminated soils. u: Golubev Ivan [ur.] Handbook of Phytoremediation, New York, United States of America: Nova Science Publishers Inc, p. 93-136
|
|
Stojanović, M., Milojković, J., Lopičić, Z., Mihajlović, M., Rajković, M., Vitorović, G. (2012) Anthropogenic sources of uranium in Serbia-risk assessment on environment and human health. u: Vasiliev Alik Ya., Sidorov Mikhail [ur.] Uranium: Characteristics, Occurrence and Human Exposure, New York, United States of America: Nova Science Publishers Inc, 46-86
|
|
Stojanović, M., Mrdaković-Popić, J., Stevanović, D., Martinović, L.J. (2006) Phosphorus Fertilizers As Source Of Uranium In Serbian Soils. Agronomy for Sustainable Development, 179-183; 26
|
3
|
Stojanović, M., Martinović, Z. (1993) Pregled analitičkih metoda za određivanje urana. u: Uticaj upotrebe fosfornih đubriva na kontaminaciju uranom, Naučni skup, 18. novembar 1992, Zbornik radova, Beograd: SANU, str. 19-29
|
|
Thomson, B.M., Smith, C.L., Busch, R.D., Siegel, M.D., Baldwin, C. (2003) Removal of Metal and Radionuclides Using Apatitet and Other Natural Sorbents. J. Envir. Engrg, 129 (6): 492-499
|
|
Tunney, H., Stojanović, M., Mrdaković-Popić, J., Mcgrath, D., Zhang, C. (2009) Relationship of soil phosphorus with uranium in grassland mineral soils in Ireland using soils from a long-term phosphorus experiment and a National soil database. J. Plant Nutr. Soil Sci, 173(3), 346-352
|
|
Usman, A., Kuzyakov, Y., Lorenz, K., Stahr, K. (2006) Remediation of a soil contaminated with heavy metals by immobilizing compounds. J. Plant Nutr. Soil Sci., 205-212; 169
|
|
Westerman, R.L. (1990) Soil Testing and Plant Analysis. Soil Science of America Book Series, p. 757; 3rd Edition
|
|
Zimdahl, R.L. (1975) Entry and movement in vegetation of lead derived from air and soil sources. u: Paper presented at 68th Annu. Meeting of the Air Pollution Control Association, Boston, MA, June 15
|
|
|
|