The previously synthesized strained distannadiyl-ansa half-sandwich complex [{k1-SntBu2- SntBu2-(η5-C5H5)}Ru(CO)2] was investigated with respect to its reactivity toward group 16 elements and bis(tert-butylisonitrile)palladium(0). All products were analyzed by multinuclear NMR spectroscopy, IR spectroscopy and elemental analysis. [{k1-SntBu2SSntBu2-(η5-C5H5)}Ru(CO)2] was furthermore characterized by X-ray diffraction.
Graphical Abstract
Insertion of Chalcogens and Bis(tert-butylisonitrile)palladium(0) into a Strained Ruthenium Half-sandwich Complex
Keywords: Ruthenium; Tin; Chalcogens; Palladium; Oxidative Addition; X-Ray Diffraction; ansa Half-sandwich Complexes
Received: 2012-9-14
Published Online: 2014-6-2
Published in Print: 2012-11-1
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