Microstructure and Corrosion Behavior of Extruded Mg-Zn-Er Alloys

Article Preview

Abstract:

The current medical technology necessitates the usage of biodegradable metals like Magnesium (Mg) as the future implant material due to the numerous benefits it can provide. Therefore, new Magnesium-based rare earth alloys targeting biomedical applications were synthesized using Disintegrated Melt Deposition (DMD) technique followed by hot-extrusion. In this investigation, Zinc (Zn) and Erbium (Er) were chosen as alloying elements to provide suitable strengthening effect and Mg-2Zn, Mg-2Zn-2Er alloys were synthesized. With the addition of alloying elements, the grain size was reduced and several MgZn intermetallics were formed. Corrosion studies of as-extruded materials were done in 0.5 wt.% NaCl solution to elucidate the microstructure-corrosion relationship. Improved corrosion resistance is seen in the alloys in comparison to pure Magnesium. Addition of Erbium is seen to improve the protectiveness of the surface film formed during immersion. Both these elements have proven to increase the corrosion potential of Mg in NaCl solution.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

1766-1771

Citation:

Online since:

December 2018

Export:

Price:

* - Corresponding Author

[1] D. Williams, New interests in magnesium., Med. Device Technol. 17 (2006) 9–10.

Google Scholar

[2] H.E. Friedrich, B.L. Mordike, Magnesium technology : metallurgy, design data, applications, Springer, (2006).

Google Scholar

[3] F. Rosalbino, E. Angelini, S. De Negri, A. Saccone, S. Delfino, Influence of the rare earth content on the electrochemical behaviour of Al–Mg–Er alloys, Intermetallics. 11 (2003) 435–441.

DOI: 10.1016/s0966-9795(03)00016-5

Google Scholar

[4] J. Zhang, W. Li, Z. Guo, Static recrystallization and grain growth during annealing of an extruded Mg–Zn–Zr–Er magnesium alloy, J. Magnes. Alloy. 1 (2013) 31–38.

DOI: 10.1016/j.jma.2013.02.012

Google Scholar

[5] J.-R. Dai, H.-M. Lu, Z.-J. Cai, C. An, Grain refining of Er added to Ti–22Al–25Nb alloy and morphology of erbium precipitates, Rare Met. 32 (2013) 5–11.

DOI: 10.1007/s12598-013-0006-4

Google Scholar

[6] S. Zhang, X. Zhang, C. Zhao, J. Li, Y. Song, C. Xie, H. Tao, Y. Zhang, Y. He, Y. Jiang, Y. Bian, Research on an Mg–Zn alloy as a degradable biomaterial, Acta Biomater. 6 (2010) 626–640.

DOI: 10.1016/j.actbio.2009.06.028

Google Scholar

[7] J. Zhang, C. Xu, Y. Jing, S. Lv, S. Liu, D. Fang, J. Zhuang, M. Zhang, R. Wu, New horizon for high performance Mg-based biomaterial with uniform degradation behavior: Formation of stacking faults, Sci. Rep. 5 (2015) 13933.

DOI: 10.1038/srep13933

Google Scholar

[8] P. Perez, E. Onofre, S. Cabeza, I. Llorente, J.A. del Valle, M.C. Garcia-Alonso, P. Adeva, M.L. Escudero, Corrosion behaviour of Mg-Zn-Y-Mischmetal alloys in phosphate buffer saline solution, Corros. Sci. 69 (2013) 226–235.

DOI: 10.1016/j.corsci.2012.12.007

Google Scholar

[9] A. Srinivasan, Y. Huang, C.L. Mendis, C. Blawert, K.U. Kainer, N. Hort, Investigations on microstructures, mechanical and corrosion properties of Mg-Gd-Zn alloys, Mater. Sci. Eng. A. 595 (2014) 224–234.

DOI: 10.1016/j.msea.2013.12.016

Google Scholar

[10] X. Zhou, Y. Huang, Z. Wei, Q. Chen, F. Gan, Improvement of corrosion resistance of AZ91D magnesium alloy by holmium addition, Corros. Sci. 48 (2006) 4223–4233.

DOI: 10.1016/j.corsci.2006.03.017

Google Scholar

[11] M. Gupta, W.L.E. Wong, Magnesium-based nanocomposites: Lightweight materials of the future, Mater. Charact. 105 (2015) 30–46.

Google Scholar

[12] M. Sun, G. Wu, W. Wang, W. Ding, Effect of Zr on the microstructure, mechanical properties and corrosion resistance of Mg–10Gd–3Y magnesium alloy, Mater. Sci. Eng. A. 523 (2009) 145–151.

DOI: 10.1016/j.msea.2009.06.002

Google Scholar

[13] G. Ben Hamu, D. Eliezer, L. Wagner, The relation between severe plastic deformation microstructure and corrosion behavior of AZ31 magnesium alloy, J. Alloys Compd. 468 (2009) 222–229.

DOI: 10.1016/j.jallcom.2008.01.084

Google Scholar

[14] G.L. Song, Corrosion and Protection of Magnesium Alloys: An Overview of Research Undertaken by CAST, Mater. Sci. Forum. 488–489 (2005) 649–652.

DOI: 10.4028/www.scientific.net/msf.488-489.649

Google Scholar