Microstructure and Crack Propagation of Electrically Conductive SiC Based Composites

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The work deals with the observation of microstructure and crack propagation from macro-indentation in a set of newly developed materials. Complex composites based on SiC matrix with 30, 40 and 50 wt. % of additives (Ti and NbC) were hot pressed at 1960 oC in air atmosphere under 30 MPa pressure for 1.5 hour. The microstructure and chemical composition were studied by SEM equipped with EDX analyzer. Hardness of the composites was evaluated by means of classic Vickers macro-indentation and fracture toughness was determined by the Anstis method. Indentation cracks were observed and their propagation was analyzed. The electrical conductivity as function of volume fraction of additives was determined.

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547-551

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March 2017

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[1] D. Baxter, A. Bellosi, and F. Monteverde, Oxidation and burner rig corrosion of liquid phase sintered SiC, J. Eur. Ceram. Soc. 20 (2000) 367–382.

DOI: 10.1016/s0955-2219(99)00160-0

Google Scholar

[2] G. Magnani, G.L. Minoccari, and L. Pilotti, Flexural strength and toughness of liquid phase sintered silicon carbide, Ceram. Int. 26 (2000) 495–500.

DOI: 10.1016/s0272-8842(99)00084-x

Google Scholar

[3] D. Sciti and A. Bellosi, Effects of additives on densification, microstructure and properties of liquid-phase sintered silicon carbide, J. Mater. Sci. 35 (2000) 3849–3855.

Google Scholar

[4] N.P. Bansal, Handbook of ceramic composites, Springer US, 2006, p.312.

Google Scholar

[5] S. Hayun, et al., Microstructure and mechanical properties of silicon carbide processed by Spark Plasma Sintering (SPS), Ceram. Int. 38 (2012) 6335–6340.

DOI: 10.1016/j.ceramint.2012.05.003

Google Scholar

[6] O. Borrero-López, et al., Microstructural evolution and contact-mechanical properties of SiC ceramics prepared colloidally with low additive content, Ceram. Int. 38 (2012) 5979–5986.

DOI: 10.1016/j.ceramint.2012.04.051

Google Scholar

[7] M. Herrmann, et al., High-temperature corrosion of silicon carbide ceramics by coal ashes, Ceram. Int. 40 (2014) 1471–1479.

DOI: 10.1016/j.ceramint.2013.07.031

Google Scholar

[8] C.J. Luis, I. Puertas, and G. Villa, Material removal rate and electrode wear study on the EDM of silicon carbide, J. Mater. Process. Technol. 164–165 (2005) 889–896.

DOI: 10.1016/j.jmatprotec.2005.02.045

Google Scholar

[9] F. Frajkorová, et al., Electrically conductive silicon carbide with the addition of TiNbC, J. Eur. Ceram. Soc. 32 (2012) 2513–2518.

DOI: 10.1016/j.jeurceramsoc.2012.02.049

Google Scholar

[10] B. Román-Manso, et al., Enhanced electrical conductivity of silicon carbide ceramics by addition of graphene nanoplatelets, J. Eur. Ceram. Soc. 35 (2015) 2723–2731.

DOI: 10.1016/j.jeurceramsoc.2015.03.044

Google Scholar

[11] G.B. Raju, B. Basu, and A.K. Suri, Thermal and electrical properties of TiB2-MoSi2, Int. J. Refract. Met. Hard Mater. 28 (2010) 174–179.

DOI: 10.1016/j.ijrmhm.2009.08.002

Google Scholar

[12] EN 843-4: Advanced Technical Ceramics - Monolithic ceramics - Mechanical properties at room temperature - Part 4: Vickers, Knoop and Rockwell superficial hardness tests. (2001).

DOI: 10.3403/00441942

Google Scholar

[13] G.R. Anstis, et al., A critical evaluation of indentation techniques for measuring fracture toughness: I Direct crack measurements, J. Am. Ceram. Soc. 46 (1981) 533–538.

DOI: 10.1111/j.1151-2916.1981.tb10320.x

Google Scholar

[14] R. Kobayashi, et al., Temperature Dependence of the Electrical Properties and Seebeck Coefficient of AlN-SiC Ceramics, J. Am. Ceram. Soc. 89 (2006) 1295–1299.

DOI: 10.1111/j.1551-2916.2005.00837.x

Google Scholar

[15] M. Fides, et al., Local Mechanical Properties of SiC - TiNbC Composite and Its Constituents, Defect Diffus. Forum 368 (2016) 158–161.

DOI: 10.4028/www.scientific.net/ddf.368.158

Google Scholar