Paper Titles

Synthesis and Characterization of Biocompatible Fe₃O₄ for Use in Cell Hyperthermia
p.476

Microstructural Evolution of a F138 Austenitic Stainless Steel after Deformation by ECAP and HPT
p.482

Morphological Comparison of PEI and PES Nanocomposite Membranes with Bentonite Clay
p.487

Analysis of the Efficiency of Surface Treatment of Bentonite Clay for Application in Polymeric Membranes
p.493

Study of Morphology Membrane of Polymeric Nanocomposites Obtained by Phases Inversion
p.498

La, Sr and Co Based Coatings Obtained on Ferritic Stainless Steel by Dip-Coating Technique
p.507

Platinum-Free Catalysts for Alkaline Polymer Electrolyte Fuel Cells
p.512

Evaluation of the Thermal Stability of Biofuel Obtained from Oil Plant Pyrolysis and Animal Fat
p.517

Processing of Silicas Formed by Slip Casting
p.525

HomeMaterials Science ForumMaterials Science Forum Vols. 775-776Study of Morphology Membrane of Polymeric...

Study of Morphology Membrane of Polymeric Nanocomposites Obtained by Phases Inversion

Article Preview

Abstract:

In this work, were obtained nanocomposite membranes polyamide66/Paraíba bentonite clay, treated with a quaternary ammonium salt in order to make it organophilic. The membranes were prepared as thin films using the technique of phase inversion from the nanocomposites obtained by solution. The membranes were characterized by X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetry (TG) and scanning electron microscopy (SEM). By means of X-ray diffractogram, it was revealed that the membranes remained organically treated clay presented exfoliated and/or partially exfoliated structure. From curves of DSC and TG, it was observed that membrane of PA66 with 3% w/w of with treatment clay showed higher thermal stability compared with the same content of clay without treatment. From the SEM photomicrographs, there was a selective layer (skin filter) on top and one porous layer at the bottom of all membranes studied. Moreover, it was verified that the presence of clay provided a significant structural modification in the membranes of polymer nanocomposites.

You might also be interested in these eBooks

20th Brazilian Conference on Materials Science and Engineering

Info:

Periodical:

Materials Science Forum (Volumes 775-776)

Pages:

498-503

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.775-776.498

Citation:

Cite this paper

Online since:

January 2014

Authors:

Keila Machado Medeiros, Taciana Regina de Gouveia Silva, Dayanne Diniz Souza Morais, Luana Rodrigues Kojuch, Edcleide Maria Araújo, Hélio Lucena Lira

Keywords:

Bentonite Clay, Membrane, Nanocomposite, Polyamide 66

Export:

RIS, BibTeX

Price:

Permissions:

Request Permissions

[1] A.C. Habert, C.P. Borges, R. Nóbrega: Membrane separation process. (1ª edição E-papers Rio de Janeiro, 2006).

[2] M. Mulder: Basic principles of membrane technology. Netherlands. (2nd Editions. Kluwer Academic Publishers 1991).

[3] P. Anadão: Membrane Science and Technology. (Artliber Editora Ltda São Paulo, 2010).

[4] F. Chavarria and D.R. Paul: Polymer. Vol. 45 (2004), p.8501.

[5] D. Kaempfer, R. Toman and R. Mulhaupt: Polymer. Vol. 43 (2002), p.2909.

[6] D.J. Lin, C.L. Chang, C.K. Lee and L.P. Cheng: European Polymer Journal Vol. 42 (2006), p.356.

[7] A.M.D. Leite, K.M. Medeiros, E.M. Araújo, L.F. Maia, H.L. Lira and R.A. Paz: Mater. Sci. Forum Vol. 660-661 (2010), p.784.

[8] E.M. Araújo, K.D. Araujo and T.R. Gouveia: Mater. Sci. Fórum Vol. 530-531 (2006), p.702.

[9] E.M. Araújo, A.D. Oliveira, R. Barbosa and T.J.A. Melo: Mater. Sci. Forum Vol. 530-531 (2006), p.709.

[10] R. Barbosa, D.D. Souza, E.M. Araújo, K.C. Nóbrega and T.J.A. Melo: Mater. Sci. Forum Vol. 660-661 (2010), p.765.

[11] K.M. Medeiros, S.V. Oliveira, E.P. Araújo, E.M. Araújo, H.L. Lira: Mater. Sci. Forum Vol. 727-728 (2012), p.1802.

[12] K.M. Medeiros, D.D.S. Morais, T.R.G. Silva, E.M. Araújo, H.L. Lira: Mater. Sci. Forum Vol. 727-728 (2012), p.1807.

[13] I.M. Kohan: Nylon plastics hanbook. (Hanser Publishers, Munich Vienna New York, 1995).

[14] L.R. Kojuch, K.M. Medeiros, D.D.S. Morais, E.M. Araújo and H.L. Lira: Mater. Sci. Forum Vol. 727-728 (2012), p.894.

[15] A.M.D. Leite , L.F. Maia , R.A. Paz , E.M. Araújo and H.L. Lira: Journ. Therm. Anal. Cal. Vol. 97 (2009), p.577.

[16] L.R. Kojuch, K.M. Medeiros, D.D.S. Morais, E.M. Araújo and H.L. Lira: Mater. Sci. Forum Vol. 727-728 (2012), p.894.

[17] X. Liu, Q. Wu and L.A. Berglund: Polymer. Vol. 43 (2002), p.4967.

[18] K.M. Medeiros, S.V. Oliveira, E.P. Araújo, E.M. Araújo and H.L. Lira: Mater. Sci. Forum Vol. 727-728 (2012), p.1802.

[19] M. Zeni, R. Riveros, J.F. Souza, K. Mello, C. Meireles and G.R. Filho: Desalination Vol. 221 (2008), p.294.

[20] A.M.D. Leite, E.M. Araújo, V.N. Medeiros, R.A. Paz and H.L. Lira, in: Abbass Hashim. (Org. ). Advances in Nanocomposite Technology. Rijeka, Croatia: InTech Publishers, 2011, p.115.

[21] A.M.D. Leite, K.M. Medeiros, E.M. Araujo, L.F. Maia, H.L. Lira and R.A. Paz: Mater. Sci. Forum Vol. 660-661 (2010), p.784.

[22] T.R.G. Silva, K.M. Medeiros, P.C.F. Menezes, E.M. Araújo and T.J.A. Melo: Mater. Sci. Forum Vol. 727-728 (2012), p.1860.

[23] K.M. Medeiros, D.D.S. Morais, T.R.G. Silva, E.M. Araújo and H.L. Lira: Mater. Sci. Forum Vol. 727-728 (2012), p.1807.

[24] K.C. Nobrega, A.M.D. Leite, E.M. Araújo, H.L. Lira and R.A. Paz: Mater. Sci. Forum Vol. 727-728 (2012), p.1706.