Thermodynamics of Solid-Phase Exchange Reactions Limiting the Subsolidus Structure of the System MgO-Al2O3-FeO-TiO2

Oksana Borisenko; Sergey Logvinkov; Galina Shabanova; Oksana Myrgorod

doi:10.4028/www.scientific.net/MSF.1038.177

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HomeMaterials Science ForumMaterials Science Forum Vol. 1038Thermodynamics of Solid-Phase Exchange Reactions...

Thermodynamics of Solid-Phase Exchange Reactions Limiting the Subsolidus Structure of the System MgO-Al₂O₃-FeO-TiO₂

Abstract:

The basis of modern materials science is multicomponent systems, on their basis it is possible to create various combinations of phases in structural materials with a set of specified properties. The investigated system MgO-Al₂O₃-FeO-TiO₂ is promising for the production of periclase-spinel refractories used as lining of rotary kilns during cement clinker firing, which are highly resistant to chemical corrosion when exposed to a gas environment and cement clinker components; thermomechanical stresses. However, in the reference literature and scientific articles, no information was found on the structure of the four-component diagram of the state of the MgO-Al₂O₃-FeO-TiO₂ system, partial elements of its structure are given only in the composition of multicomponent systems [1-3]. Thus, research to the study of the subsolidus structure of the MgO-Al₂O₃-FeO-TiO₂ system, which is the physicochemical basis for the development of compositions of periclase-spinel refractories, is urgent.

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Periodical:

Materials Science Forum (Volume 1038)

Pages:

177-184

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.1038.177

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Online since:

July 2021

Authors:

Oksana Borisenko*, Sergey Logvinkov, Galina Shabanova, Oksana Myrgorod

Keywords:

Multicomponent Systems, Subsolidus Structure, Thermodynamic Analysis

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