Micro-Indentation Test and Morphology of Electron Beam Irradiated HDPE

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Abstract:

Cross-linking is a process in which polymer chains are associated through chemical bonds. The cross-linking level can be adjusted by the irradiation dosage and often by means of a cross-linking booster. The polymer additional cross-linking influences the surface nanoand micro layers in the way comparable to metals during the thermal and chemical-thermal treatments. The aim of this paper is to study the effect of ionizing radiation with different doses (33, 66 and 99 kGy), on micro-mechanical properties of polyethylene (HDPE) and compare these results with those of non-irradiated samples. Influence of the cross-linking by β – radiation of the tested HDPE on micro-indentation test and morphology was investigated. Micro-mechanical properties increased with increasing value of the dose of irradiation material. The changes were examined and confirmed by X-ray diffraction.

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189-192

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September 2015

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[1] J.G. Drobny, Radiation Technology for Polymers, CRC Press, New York, (2003).

Google Scholar

[2] M. Ovsik, D. Manas, M. Manas, M. Stanek, M. Hribova, K. Kocman, D. Samek, Irradiated Polypropylene Studied by Microhardness and WAXS, Chemicke listy 106 (2012), 507-510.

DOI: 10.1016/j.tsf.2012.09.051

Google Scholar

[3] O. N. Tretinikov, S. Ogata, Y. Ikada, Surface Crosslinking of Polyethylene by Electron Beam Irradiation in Air, Polymer 39 24 (1998), 6115 - 6120.

DOI: 10.1016/s0032-3861(98)00075-5

Google Scholar

[4] Z. Xiaohu, Y. Hongmei, S. Yihu, Influence of Crosslinking on Crystallization, Rheological, and Mechanical Behaviors of High Density Polyethylene/Ethylene-Vinyl Acetate Copolymer Blends, Polymer Engineering and Science 54 12 (2014), 2848 - 2858.

DOI: 10.1002/pen.23843

Google Scholar

[5] P. Y. Chen, C. C. Chen, J. P. Harmon, S. Lee, The Effect of Gamma Radiation on Hardness Evolution in High Density Polyethylene at Elevated Temperatures, Materials Chemistry and Physics 146 3 (2014), 369 - 373.

DOI: 10.1016/j.matchemphys.2014.03.039

Google Scholar

[6] G. Zamfirova, V. Gaydarov, T. Zaharescu, L. G. Silva, Microindentation study of Electron Beam Irradiated Polyamide Samples, Chemicke Listy 104 (2010), 283-286.

Google Scholar

[7] W.C. Oliver, G.M. Pharr, Measurement of Hardness and Elastic Modulus by Instrumented Indentation, Journal of Materials Research 19 (1) (2004), 1564 – 1583.

Google Scholar

[8] D. Manas, M. Hribova, M. Manas, M. Ovsik, Stanek, Effect of Beta Irradiation on Morphology and Microhardness of Polypropylene Thin Layers, Thin Solid Films 530 (2013), 49-52.

DOI: 10.1016/j.tsf.2012.09.051

Google Scholar